Biomass is one of the renewable energy resources which can be used instead of fossil fuels to diminish environment pollution and emission of greenhouse gases. Hydrogen as a biomass is considered as an alternative fuel which can be derived from a variety of domestically available primary sources. In this paper, a hydrogen and electricity co-generation plant with rice husk is proposed. Rice husk with water vapor and oxygen produces syngas in gasifier. In this design, electricity is generated by using two Rankine cycles. The Results show that the net electric efficiency and hydrogen production efficiency are 1.5% and 40.0%, respectively. Hydrogen production is 1.316 kg/s in case which carbon dioxide is gathered and stored. The electricity generation is 5.923 MWe. The main propose of implementing Rankine cycle is to eliminate hydrogen combustion for generating electricity and to reduce NO production. Furthermore, three kinds of membranes are studied in this paper. Crown Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.