화학공학소재연구정보센터
Journal of Chemical Physics, Vol.108, No.14, 5913-5920, 1998
Critical adsorption in the undersaturated regime : Scaling and exact results in Ising strips
Critical adsorption for weak surface field h(1) is reconsidered. On the basis of physical heuristic arguments, approximate behavior of the scaling function is derived. New form of a scaling for weak h(1) in finite systems is proposed and verified by testing against exact results obtained for this purpose in the 2D Ising strips, For weak h(1) we find the approximate behavior of adsorption Gamma similar to tau(beta-Delta 1) for the reduced temperatures h(1)(1/Delta 1)similar to tau much less than 1. This behavior is consistent with experimental data [N. S. Desai, S. Peach, and C. Franck, Phys. Rev. E 52, 4129 (1995)] obtained for tau=10(-5), and is in a very good agreement with exact results in the 2D Ising strip.