This paper reports on a hydrogen storage material of poly(methyl acrylate) and methylamine borane (PMA/MeAB) composite, which is synthesized by a simple solution-blending process at room temperature. The thermal decomposition process of the as-prepared composite is investigated by temperature programmed desorption/mass spectrometer (TPD/MS), thermogravimetry (TG) measurements and water displacement method. It is found that PMA/MeAB100 (100 mg PMA with 100 mg MeAB) starts to release H-2 at the temperature of 90.5 degrees C with the dehydrogenation peak centered at 120.7 degrees C. This is about 20 degrees C lower than that of neat MeAB. Meanwhile, the evaporation of MeAB and the volatile byproducts from the dehydrogenation stage of PMA/MeAB100 are also suppressed. The present result shows that the dehydrogenation property of MeAB is enhanced by using PMA/MeAB composite. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.