In this work, glycerol was used for hydrogen production by supercritical water gasification. Experiments were conducted in a continuous flow tubular reactor at 445 similar to 600 degrees C, 25 MPa, with a short residence time of 3.9 similar to 9.0 s. The effects of reaction temperature, residence time, glycerol concentration and alkali catalysts on gasification were systematically studied. The results showed that the gasification efficiency increased sharply with increasing temperature above 487 degrees C. A short residence time of 7.0 s was enough for 10 wt% glycerol gasification at 567 degrees C. With the increase of glycerol concentration from 10 to 50 wt%, the gasification efficiency decreased from 88% to 71% at 567 degrees C. The alkali catalysts greatly enhanced water-gas shift reaction and the hydrogen yield in relation to catalysts was in the following order: NaOH > Na2CO3 > KOH > K2CO3. The hydrogen yield of 4.93 mol/mol was achieved at 526 degrees C with 0.1 wt% NaOH. No char or tar was observed in all experiments. The apparent activation energy and apparent pre-exponential factor for glycerol carbon gasification were obtained by assuming pseudo first-order kinetics. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.