International Journal of Hydrogen Energy, Vol.37, No.1, 921-925, 2012
Electrochemical performance of cone-shaped anode-supported segmented-in-series SOFCs fabricated by gel-casting technique
Cone-shaped tubular anode substrates were prepared successfully by using gel-casting technique. An 8 mol% yttria-stabilized zirconia (YSZ) electrolyte film was coated onto the green body of the anode by dip-coating technique and then the bilayer was co-sintered at 1350 degrees C for 4 h. La0.7Sr0.3MnO3 (LSM)-YSZ was brush painted on the surface of the YSZ film as cathode. Such a single NiO-YSZ/YSZ/LSM-YSZ fuel cell was tested from 600 to 800 degrees C with humidified hydrogen (3%H2O, 100 mL/min) as fuel and ambient air as oxidant. Initial results showed that at 800 degrees C the open circuit voltage (OCV) approached 1.0 V and the maximum power density was 900 mW cm(-2). The impedance measurements measured under open circuit condition revealed that at 800 degrees C the ohmic resistance of the cell was 0.1 Omega cm(2) and the electrode polarization resistance was 0.4 Omega cm(2). A four-cell-stack based on the above-mentioned cone-shaped tubular anode-supported SOFC was assembled and tested. The OCV and maximum output power at 800 degrees C were 3.2 V and 3.4 W, respectively. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.