Ba1-xSrxCo0.8Fe0.2O3-delta (x = 0.3-0.9) perovskite oxides have been studied as cathode material for intermediate temperature solid oxide fuel cells (IT-SOFCs). The structural characteristics, temperature dependent weight loss, thermal expansion, electrical conductivity, and electrochemical properties in combination with YSZ electrolyte together with an SDC buffer layer were characterized by X-ray diffraction (XRD), thermogravimetric analysis (TG), dilatometry, DC four probe conductivity measurement and electrochemical impedance spectroscopy (EIS) techniques respectively. XRD study revealed the lattice parameter and unit cell volume decrease with increase in Sr+2 content at the A-site. TEC and electrical conductivity were found to increase with increasing Sr+2 content. Electrical conductivity was found to be dependent on the thermal history of the samples. Polarization resistance of the samples with SDC buffered YSZ electrolyte decreased with increasing Sr+2 content which was ascribed to the higher conductivity with improved oxygen adsorption/desorption and oxygen ions diffusion processes. The intrinsic oxygen reduction reaction rate also increased with Sr+2 content at the A-site. The exchange current for intrinsic oxygen reduction reaction at 700 degrees C was found to be 50.0 mA cm(-2) for Ba0.3Sr0.7Co0.8Fe0.2O3-delta; a value which is about 50% higher than that for Ba0.5Sr0.5Co0.8Fe0.2O3-delta, a widely studied cathode material. Therefore, the present composition may be a potential cathode material for IT-SOFC application. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.