A novel dual-bed system was designed to produce hydrogen through photocatalytic water splitting. The system was comprised of a photocatalytic reaction bed and a regeneration bed. Aqueous KI solution and Pt-loaded TiO(2) constituted the photocatalytic reaction bed where hydrogen was produced; meanwhile the hole scavenger iodide ion was oxidized into I(2). The effluent containing I(2) from the photocatalytic bed entered the regeneration bed and passed through a Cu(2)O layer where I(2) was reduced to I(-). The regeneration bed effluent was then recycled to the photocatalytic reaction bed. Since the hole scavenger KI in the photocatalytic bed was constantly kept at a high level through the continuous reduction of I(2) in the regeneration bed, steady production of hydrogen was achieved in the dual-bed system for a much longer period as compared to a single-bed system without regeneration. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.