화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.36, No.12, 7229-7233, 2011
Novel SrTixCo1-xO3-delta cathodes for low-temperature solid oxide fuel cells
The SrTixCo1-xO3-delta (STC, x = 0.05, 0.1, 0.15, 0.2) perovskite-type oxides synthesized by the polymerized complex (PC) method have been investigated as cathode materials for low-temperature solid oxide fuel cells (SOFCs) with composite electrolyte for the first time. Thermogravimetry differential thermal analysis (TG-DTA) shows the crystallization of SrTi0.1Co0.9O3-delta occurs at 780 degrees C. The oxides have been stabilized to be a cubic perovskite phase after the B-site is doped with Ti ion. The maximum power density reaches as high as 613 mW cm(-2) at 600 degrees C for SOFC with SrTi0.2Co0.8O3-delta cathode. The maximum power densities increase with the increasing Ti content in the cathode, which can be attributed to the enhancement of conductivity and electrocatalytic activity. The stability of the fuel cell with SrTi0.1Co0.9O3-delta cathode has been examined for 18 h at 600 degrees C. Only a slight decline in the cell performance can be observed with increasing time. The high performance cathodes together with the low-cost fabrication technology are highly encouraging for development of low-temperature SOFCs. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.