International Journal of Hydrogen Energy, Vol.35, No.23, 13073-13077, 2010
Effects of the addition of ZnO and Y2O3 on the electrochemical characteristics of a Ni(OH)(2) electrode in nickel-metal hydride secondary batteries
This study examined the effects of the addition of ZnO and Y2O3 on the electrochemical characteristics of a Ni(OH)(2) electrode in nickel metal hydride (Ni-MH) secondary batteries The discharge capacity of the electrode was less affected by the addition of ZnO and Y2O3 at a 0 2 C rate and 25 C However the addition of Y2O3 deteriorated the discharge capacity and the cycle life of the electrode by increasing the charge transfer resistance of the electrode at an increased C rate of 1 C and 25 degrees C Under severer conditions at 1 C rate and 60 C the electrode materials were separated from the current collector and accordingly the discharge capacity was abruptly degraded with cycling for the electrodes comprising only 4 wt% ZnO or 4 wt% Y2O3 In contrast, the electrodes containing both 2 wt% ZnO and 2 wt% Y2O3 exhibited stable discharge capacity with cycling and excellent cycle life due to the high overvoltage for oxygen evolution The present results indicate that the addition of ZnO and Y2O3 with an optimum composition suppresses oxygen evolution in the interfaces between active materials and the current collector and improves the cycle life of the electrode (C) 2010 Professor T Nejat Veziroglu Published by Elsevier Ltd All rights reserved
Keywords:Nickel-metal hydride secondary battery;ZnO;Y2O3;Discharge capacity;Cycle life;Oxygen evolution