Autothermal reforming of methane includes steam reforming and partial oxidizing methane Theoretically the required endothermic heat of steam reforming of methane could be provided by adding oxygen to partially oxidize the methane Therefore combining the steam reforming of methane with partial oxidation may help in achieving a heat balance that can obtain better heat efficacy Membrane reactors offer the possibility of overcoming the equilibrium conversion through selectively removing one of the products from the reaction zone For instance only can hydrogen products permeate through a palladium membrane which shifts the equilibrium toward conversions that are higher than the thermodynamic equilibrium In this study autothermal reforming of methane was carried out in a traditional reactor and a Pd/Ag membrane reactor, which were packed with an appropriate amount of commercial Ni/MgO/Al(2)O(3) catalyst A power analyzer was employed to measure the power consumption and to check the autothermicity The average dense Pd/Ag membrane thickness is 24 3 mu m which was coated on a porous stainless steel tube via the electroless palladium/silver plating procedure The experimental operating conditions had temperatures that were between 350 degrees C and 470 degrees C pressures that were between 3 atm and 7 atm and O(2)/CH(4) = 0-0 5 The effects of the operating conditions on methane conversion permeance of hydrogen H(2)/CO selectivities of CO(x) amount of power supply and the carbon deposition of the catalyst after the reaction is thoroughly discussed in this paper The experimental results indicate that an optimum methane conversion of 95% with a hydrogen production rate of 0 093 mol/m(2) S can be obtained from the autothermal reforming of methane at H(2)O/CH(4) = 1 3 and O(2)/CH(4) near 0 4 at which the reaction does not consume power and the catalysts are not subject to any carbon deposition (C) 2010 Professor T Nejat Veziroglu Published by Elsevier Ltd All rights reserved