여러 가지 사슬을 가진 poly(alkylene carbonate)의 합성

이윤배; 김선길; 신상철; Yoon Bae Lee; Sun Kil Kim; Sang Chol Shin

Journal of the Korean Industrial and Engineering Chemistry, Vol.11, No.2, 195-198, April, 2000

Export Citation

여러 가지 사슬을 가진 poly(alkylene carbonate)의 합성

Synthesis of Poly(alkylene carbonate)s with Various Chains

이윤배^†, 김선길, 신상철

순천향대학교 화학공학부, 아산 336-745

Yoon Bae Lee^†, Sun Kil Kim, and Sang Chol Shin

Department of Chemical Engineering, Soonchunhyang University, 53-1, Eupnaeri, Shinchangmyun, Asan 336-745, Korea

E-mail:

초록

이산화탄소를 이용하여 여러 가지 사슬을 가진 새로운 poly(alkylene carbonate)를 합성하였다. Cyclopentene oxide, 1-Hexene oxide, 1-Dodecene oxide를 이용한 새로운 카보네이트가 비교적 높은 분자량으로 합성되어 그 유리 전이 온도를 측정하여 구조와 연관하여 비교하였다. 고리구조를 주쇄에 가질 경우 유리 전이 온도는 현저하게 증가하였고, 긴 알킬 사슬을 가진 경우 유리 전이 온도는 영하에 분포되는 것을 관찰하였다.

New poly(alkylene carbonate)s with various alkyl chain have been synthesized with carbon dioxide and cyclopentene oxide, 1-hexene oxide and 1-dodecene oxide. Their molecular weight are rather high enough to give proper mechanical properties. The glass transition temperatures of the poly(alkylene carbonate)s are correlated with their structure. Higher transition temperature was observed in case of cyclic chain, however those are lied under 0℃ in case of linear alkyl chain.

Keywords:poly(alkyene carbonate);CO₂;cyclopentene oxide. 1-hexene oxide;1-dodecene oxide

[References]

Park JW, Chem. Ind. Technol., 11, 2 (1993)
Lee SW, Lee JH, Chem. Ind. Technol., 11, 9 (1993)
Park SU, Jang JS, Lee GW, Chem. Ind. Technol., 12(1), 17 (1994)
Inoue S, Koinuma H, Tsuruta T, Polym. Lett., 7, 287 (1969)
Inoue S, Koinuma H, Tsuruta T, Makromol. Chem., 130, 210 (1969)
Chem. Sytem, Poly(alkylene carnonate), Process Evaluation Research Planning (1987)
Kawaguchi T, Nakano M, Juni K, Inoue S, Yoshida Y, Chem. Pharm. Bull. Jpn., 31, 1400 (1983)
Dixon D, Ford M, J. Polym. Sci. C: Polym. Lett., 18, 599 (1980)
Hino Y, Yoshida Y, Inoue S, Polym. J., 16, 159 (1984)
Aida T, Inoue S, J. Am. Chem. Soc., 105, 1305 (1983)
U.S. Patent, 3,706,713 (December 19, 1972) to Shell (1972)
Tao JS, Air Product & Chemicals Internal Report (1989)
Lee YB, J. Soonchunghyang Univ., 16, 999 (1993)
Lee YB, Polym.(Korea), 19(1), 35 (1995)
Lee YB, Choi JH, J. Korean Ind. Eng. Chem., 7(5), 813 (1996)
Bronk JM, Riffle JS, Polym. Prepr., 35, 85 (1994)
Aida T, Ishikawa M, Inoue S, Macromolecules, 19, 8 (1986)
Sperling LH, "Introduction to Physical Polymer Science, p. 254-272, John Wiley & Sons, New York (1986)
Fox TG, Bull. Am. Phys. Soc., 1, 123 (1956)

[Referenced By]

[1] Park JW, Chem. Ind. Technol., 11, 2 (1993)

[2] Lee SW, Lee JH, Chem. Ind. Technol., 11, 9 (1993)

[3] Park SU, Jang JS, Lee GW, Chem. Ind. Technol., 12(1), 17 (1994)

[4] Inoue S, Koinuma H, Tsuruta T, Polym. Lett., 7, 287 (1969)

[5] Inoue S, Koinuma H, Tsuruta T, Makromol. Chem., 130, 210 (1969)

[6] Chem. Sytem, Poly(alkylene carnonate), Process Evaluation Research Planning (1987)

[7] Kawaguchi T, Nakano M, Juni K, Inoue S, Yoshida Y, Chem. Pharm. Bull. Jpn., 31, 1400 (1983)

[8] Dixon D, Ford M, J. Polym. Sci. C: Polym. Lett., 18, 599 (1980)

[9] Hino Y, Yoshida Y, Inoue S, Polym. J., 16, 159 (1984)

[10] Aida T, Inoue S, J. Am. Chem. Soc., 105, 1305 (1983)

[11] U.S. Patent, 3,706,713 (December 19, 1972) to Shell (1972)

[12] Tao JS, Air Product & Chemicals Internal Report (1989)

[13] Lee YB, J. Soonchunghyang Univ., 16, 999 (1993)

[14] Lee YB, Polym.(Korea), 19(1), 35 (1995)

[15] Lee YB, Choi JH, J. Korean Ind. Eng. Chem., 7(5), 813 (1996)

[16] Bronk JM, Riffle JS, Polym. Prepr., 35, 85 (1994)

[17] Aida T, Ishikawa M, Inoue S, Macromolecules, 19, 8 (1986)

[18] Sperling LH, "Introduction to Physical Polymer Science, p. 254-272, John Wiley & Sons, New York (1986)

[19] Fox TG, Bull. Am. Phys. Soc., 1, 123 (1956)