Stainless steel is a potential material to be used as the bipolar plate for proton exchange membrane fuel cell (PEFC) because of its suitable physical and mechanical properties. Several coating techniques have been applied to improve its corrosion resistance. But seldom study is focused on the microstructure evolution with corrosion. In the present study, the use of TiN-coated stainless steel as the bipolar plate is evaluated. Two surface coating techniques, pulsed bias arc ion plating (PBAIP) and magnetron sputtering (MS), are adoped to prepare the TiN-coated stainless steel. Their corrosion resistances and electrical conductivities of the coated substrates are evaluated. The performance shows strong dependance on microstructural characteristics. The corrosion of SS304/Ti(2)N/TiN prepared by MS mainly occurs on the grain boundary. The corrosion of SS304/TiN prepared by PBAIP mainly takes place from the large particles on the coating. The Ti(2)N/TiN multilayer coating provides superb corrosion protective layer for stainless steel. Both the TiN and Ti(2)N/TiN coatings provide low contact resistance. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.