초산금속 존재하 PET 올리고머 형성에 따른 반응속도

정병옥; 김태정; 박상순; 정석진; 김진도; 이영우; 이경원; Byung Ok Jung; Tae Jeong Kim; Sang Soon Park; Suk Jin Chung; Jin Do Kim; Young Woo Lee; Gyong Won Lee

Journal of the Korean Industrial and Engineering Chemistry, Vol.11, No.2, 157-162, April, 2000

Export Citation

초산금속 존재하 PET 올리고머 형성에 따른 반응속도

Kinetics for the Catalyzed Formation of PET Oligomer with Metal Acetates

정병옥, 김태정, 박상순, 정석진^†, 김진도¹, 이영우¹, 이경원¹

서울산업대학교 응용화학공학부, 서울 139-743
¹충주대학교 공업화학과, 충북 380-702

Byung Ok Jung, Tae Jeong Kim, Sang Soon Park, Suk Jin Chung^†, Jin Do Kim¹, Young Woo Lee¹, and Gyong Won Lee¹

School of Applied Chemistry and Chemical Engineering, Seoul University of Technology, Seoul 139-743, Korea
¹Department of Industrial Chemistry, Chungju National University, Chungbuk 380-702, Korea

E-mail:

초록

Dimethyl terephthalate (DMT)와 ethylene glycol (EG)간의 에스케르교환반응시 다양한 metal acetate를 이용하여 반응온도 190~210℃ 범위에서 반응속도를 조사하였다. 또한 반응속도식에 따른 온도의존성을 살펴보았다. 온도의존성을 언급된 반응속도 모델식을 이용하여 실험자료에 적용한 결과 잘 일치함을 알았다. 금속촉매하 에스테르교환반응에 관한 촉매활성은 Pb >> Mn > Co > Zn > Cd > Mg > Ba > Cs > K > Cu 순으로 나타났다.

Transesterification reaction kinetics between dimethyl terephthalate (DMT) and ethylene glycol (EG) has been investigated in the presence of various metal acetates as catalyst. Temperature dependence on the reaction kinetics was also studied. A kinetic model was developed for the catalyzed reaction, and the experimental results showed a good agreement with it. Catalytic activity on the metal-catalyzed transesterification was found to be in the order of Pb >> Mn > Co > Zn > Cd > Mg > Ba > Cs > K > Cu.

Keywords:transesterification;extent of reaction;metal-catalyzed reaction;catalytic activity

[References]

Ravindranath K, Mashelkar RA, Chem. Eng. Sci., 41, 2197 (1986)
Arunpal A, Chem. Age India., 29, 733 (1978)
Datye KV, Raje HM, J. Appl. Polym. Sci., 30, 205 (1985)
Yamanis J, Adelman M, J. Polym. Sci. A: Polym. Chem., 14, 1961 (1976)
Walker CC, J. Polym. Sci. A: Polym. Chem., 21, 623 (1983)
Kotliar AM, J. Polym. Sci. Macromol. Rev., 16, 367 (1981)
Challa G, Rec. Trav. Chim., 79, 90 (1960)
Shah TH, Bhatty JI, Gamlen GA, Dollimore D, Polymer, 25, 1333 (1984)
Tomita K, Ida H, Polymer, 16, 185 (1975)
Tomita K, Ida H, Polymer, 14, 55 (1973)
Wang CS, Sun YM, J. Polym. Sci. A: Polym. Chem., 32(7), 1305 (1994)
Aharoni SM, Forbes CE, Hammond WB, Hindenlang DM, Mares F, O'brien K, Sedgwick RD, J. Polym. Sci. A: Polym. Chem., 24, 1281 (1986)
Otton J, Ratton S, J. Polym. Sci. A: Polym. Chem., 26, 2183 (1988)

[1] Ravindranath K, Mashelkar RA, Chem. Eng. Sci., 41, 2197 (1986)

[2] Arunpal A, Chem. Age India., 29, 733 (1978)

[3] Datye KV, Raje HM, J. Appl. Polym. Sci., 30, 205 (1985)

[4] Yamanis J, Adelman M, J. Polym. Sci. A: Polym. Chem., 14, 1961 (1976)

[5] Walker CC, J. Polym. Sci. A: Polym. Chem., 21, 623 (1983)

[6] Kotliar AM, J. Polym. Sci. Macromol. Rev., 16, 367 (1981)

[7] Challa G, Rec. Trav. Chim., 79, 90 (1960)

[8] Shah TH, Bhatty JI, Gamlen GA, Dollimore D, Polymer, 25, 1333 (1984)

[9] Tomita K, Ida H, Polymer, 16, 185 (1975)

[10] Tomita K, Ida H, Polymer, 14, 55 (1973)

[11] Wang CS, Sun YM, J. Polym. Sci. A: Polym. Chem., 32(7), 1305 (1994)

[12] Aharoni SM, Forbes CE, Hammond WB, Hindenlang DM, Mares F, O'brien K, Sedgwick RD, J. Polym. Sci. A: Polym. Chem., 24, 1281 (1986)

[13] Otton J, Ratton S, J. Polym. Sci. A: Polym. Chem., 26, 2183 (1988)