A hydrogen internal combustion engine (HICE) wastes more heat, and producing nearly three times more water than a conventional engine. This paper describes the principle behind a novel waste heat recovery sub-system that exploits the water produced by an HICE as the working fluid for an open-cycle power generation system based on the Rankine cycle. Water from the HICE exhaust is superheated by the waste heat from the HICE and used to produce power in a steam expander. A fundamental thermodynamic model shows the contribution of the sub-system to the overall thermal efficiency of the HICE at various engine speeds, with and without a condenser. The results show that the condenser is not cost-effective and that the overall thermal efficiency with the proposed sub-system is 27.2% to 33.6%, representing improvements of 2.9% to 3.7%, at engine speeds of 1500 to 4500 rpm. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.