The sulphur-iodine thermochemical cycle for hydrogen production has been investigated by ENEA (Agency of New Technologies, Energy and Environment, Italy) over the last 5 years, with a particular focus on chemical aspects. Regarding the hydrogen iodide decomposition, four gamma-alumina-supported nickel catalysts were produced and characterized, and then tested in terms of catalytic activity and stability by means of a tubular quartz reactor. In particular, the relationship between catalytic activity and preparation procedure was investigated. From the experimental data acquired, it can be concluded that three of the four catalysts tested demonstrated high catalytic activity, since hydrogen iodide conversion was almost coincident with the theoretical equilibrium value. On the other hand, for all the catalysts, a gradual but considerable deactivation phenomenon was observed at 500 degrees C, while at a temperature higher than 650 degrees C the catalytic activity was recovered. (C) 2008 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.