화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.32, No.18, 5088-5093, 2007
Method of gasification in IGCC system
A coal gasifier is designed to operate at the temperature range of 1200-1300 degrees C. The 1200 degrees C sets the lower limit to the carbon reforming efficiency of the high temperature reformer, and the 1300 degrees C is the lower limit of the fluid temperature of coal slags, below which they may be collected as non-fluid slag. The gasifier is connected to two syngas burners where a portion of product syngas is combusted with O-2 gas and produce ultra hot H2O and CO2 gases, these two gases enter into the gasifier and maintain the gasifier temperature at above 1200 degrees C and reform carbon into syngas. The temperature of the gasifier is controlled by the flow of O-2 gas into the syngas burner, where O-2 gas is completely consumed and none left to enter into the gasifier. This removes any possibility of forming oxidated products, and compressed CO2 gas spray coal powder into the gasifier column and non-fluid slag is collected at the bottom. A higher level integration of oxidation-reduction cycle is shown for a IGCC system, wherein the exhaust gas of syngas turbine drives the reduction reaction of coal gasification. A smooth and uniform temperature control within the gasifier assures high efficiency of carbon reforming and quality of product syngas. Conventional Lurgi gasifier relies on its large heat capacity and accumulating coal slag along the inner walls of the gasifier has made the gasifier bigger, lately as large as a three story building. The gasifier of the present design is constructed much smaller in its size, but with greater reforming efficiency. (c) 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.