화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.28, No.3, 303-309, 2003
Hydrogen desorption kinetics in intermetallic compounds C2, C5(1) and C5(2) with Laves phase structure
Desorption kinetics for the commercial hydride forming alloys C2, C5(1) and C5(2) with Laves phase structure were studied. Isothermal measurements in a close volumetric system were carried out in temperature range of -20-20degreesC. The normalized pressure dependence method (NPDM) was applied to interpret the experimental data and to compare with each other. The NPDM approach and its possibility were discussed. The kinetics was found to be very fast for the studied hydrides. Assuming first order for desorption processes the kinetic parameters were shown to correspond of the following: k = 0.67, 0.43 and 1.08 s(-1) at 20degreesC for C2, C5(1) and C5(2), respectively. Activation energy values in the above-mentioned temperature range were derived to be E-a = 33, 40 and 30 kJ/mol for C2, C5(1) and C5(2), respectively. The hydrides thermodynamic equilibrium parameters DeltaH and DeltaS as well as maximum and minimum plateau P-eq's were also derived. The specific thermal cooling power output W, was measured experimentally for C52. One has valued about 1.5 kW per I kg hydralloy for 2 min. These results were compared with those for commercial alloys HY STOR 205 and HY STOR 209. (C) 2002 International Association for Hydrogen Energy. Published by Elsevier Science Ltd. All rights reserved.