In this paper, we report electrochemical charge/discharge of hydrogen for a pellet metal-hydride electrode using an MmNi(5-x)M(x) alloy as active material. Strong dependence of temperature and discharge current was found for electrochemical applications. Pellet electrode showed good stability over 250 charge/discharge cycles. Self-discharge studies were carried out on completely charged electrode. The capacity of this electrode to absorb/desorb hydrogen could be defined as a stochastic function of some variables like temperature, cycling and discharge current conditions. More studies are in progress for calculating electrochemical parameters in these metal-hydride electrode systems.