Hydrogen storage alloys are a group of new functional intermetallics which can be used in heat pumps, catalysts, hydrogen sensors and Ni/MH batteries. The development of Ni/MH (Metal Hydride) batteries based on MH negative electrodes has seen considerable activity in recent years. Batteries based on such hydride materials have some major advantages over the more conventional lead-acid and nickel-cadmium systems. These advantages include: high-energy density; high-rate capability; tolerance to overcharge and over-discharge; the lack of any poisonous heavy metals; and no electrolyte consumption during charge/discharge cycling. The most important electrochemical characteristics of the hydrogen storage compounds used in these batteries include capacity, cycle lifetime, exchange current density and equilibrium potential. These characteristics can be changed by designing the composition of the hydrogen storage alloy to provide optimum performance of the Ni/MH batteries. The electrochemical behaviour of such intermetallics depends on the types of intermetallics (mainly AB(2) and AB(5)), microstructure, the nature and amount of each element in the intermetallic compound, and the electrochemical process(es) taking place. The addition of some highly electrocatalytic materials for the hydrogen evolution reaction (h.e.r.) are beneficial in generating optimum performance for the MH electrodes. In this paper, we present some recent results on the electrochemical behaviour of such compounds and the mechanisms of the electrochemical reactions.