콘크리트 - 포리머 복합재료 개발 (II) - 폴리머(레진) 콘크리트의 물성 -

황의환; 황택성; 길덕수

Journal of the Korean Industrial and Engineering Chemistry, Vol.10, No.7, 1066-1072, November, 1999

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콘크리트 - 포리머 복합재료 개발 (II) - 폴리머(레진) 콘크리트의 물성 -

Development of Concrete-Polymer Composite(II)-Physical Properties of Polymer(Resin) Concrete-

황의환, 황택성, 길덕수

초록

고기능성 건설재료로 활용하기 위하여 불포화폴리에스테르수지를 사용한 폴리며 콘크리트으 물성에 대하여 조사하였다. 탄산칼슘(충전제)의 첨가량(5~20 wt %)과 세골재의 첨가량(10~50 wt %)에 따라 다양한 배합의 공시체를 제작하여 압축 및 휨강도, 흡수시험, 내열수성시험, 내산성시험, 세공분포측정 및 SEM에 의한 미세조직 관찰등을 실시하였다. 그 결과 폴리머 콘크리트의 압축강도와 휨강도는 시멘트 콘크리트보다 4배 정도 향상되었고, 흡수율은 1/100로 감소되었으며, 내산성시험에 의한 중량감소율은 1/27로 현저히 감소되었다. 내열수성시험후에 측정한 폴리머 콘크리트의 압축 및 휨강도는 모두 내열수성시험전에 측정한 강도에 비하여 67%, 47%로 각각 감소되었으며 폴리머결합재의 분해에 의하여 세공량과 세공율은 크게 증가되었다.

The physical properties of polymer concrete were investigated for development of high-performance construction materials. Various specimens of polymer concrete were prepared using unsaturated polyester resin as the polymer-binder with the various dosage of calcium carbonate as microfiller (5~20 wt %) and fine aggregate(10~50 wt %). For the evaluation of the physical properties of polymer concretes,tests such as compressive strength, flexural strength, water absorption test, hot water immersion test, acid resistance test and pore size distribution analysis were conducted. As a result, it is concluded that compressive and flexural strengths of polymer concretes increased up to 4 times than those of conventional cement concrete. Whereas the compressive and flexural strengths of polymer concretes tested after hot water immersion, compared with those of polymer concretes tested before hot water immersion, decreased about 67%, 47%, respectively. By hot water immersion, total pore volume and porosity(%) of polymer concretes were remarkable increased due to decomposition of polymer binder. And also, it is showed that water absorption(%) and weight loss(%) of polymer concrete specimens by acid immersion, compared with those of ordinary portland cement concrete, decreased about 1/100, 1/27, respectively.

Keywords:polymer concrete;unsaturated polyester resin;compressive strength;pore volume

[References]

Ohama Y, Notoya K, Miyake M, Transactions Jpn. Concrete Inst., 7, 165 (1985)
Kasai Y, Matsui I, Fukushima Y, Int. Cong. Polym. Concrete, 3, 178 (1981)
Okada K, Ohama Y, Int. Cong. Polym. Concrete, 3, 3 (1981)
Fowler DW, Taylor TU, Int. Cong. Polym. Concrete, 6, 10 (1990)
大濱嘉彦, コソクリ-ト工學, 28, 5 (1990)
Fowler DW, ACI J., 83, 798 (1986)
海野幸則, 合成樹脂工業, 35, 126 (1988)
官永晴治, 化學經濟, 33, 14 (1986)
Fowler DW, Int. Cong. Polym. Concrete, 8, 13 (1995)
Paturoev VV, Trambovetsky VP, Int. Cong. Polym. Concrete, 8, 451 (1995)
Ohama Y, Demura M, Komiyama M, J. Soc. Mater. Sci., 29, 266 (1980)
Mani P, Gupta AK, Krishnamoorthy S, Int. J. Adhesion Adhesives, 7, 157 (1987)
Ohama Y, コソクリ-ト工學, 26, 70 (1988)
小林恒己, 藤田晃弘, 鋪裝, 21, 9 (1986)
Ohama Y, コソクリ-ト工學, 28, 5 (1990)
Kobaashi K, Ito T, Int. Cong. Polym. Concrete, 1, 236 (1976)
Ohama Y, ポリマ-ダイヅェスト, 35, 47 (1983)
Ohama Y, 材料, 36, 679 (1987)

[Referenced By]

[1] Ohama Y, Notoya K, Miyake M, Transactions Jpn. Concrete Inst., 7, 165 (1985)

[2] Kasai Y, Matsui I, Fukushima Y, Int. Cong. Polym. Concrete, 3, 178 (1981)

[3] Okada K, Ohama Y, Int. Cong. Polym. Concrete, 3, 3 (1981)

[4] Fowler DW, Taylor TU, Int. Cong. Polym. Concrete, 6, 10 (1990)

[5] 大濱嘉彦, コソクリ-ト工學, 28, 5 (1990)

[6] Fowler DW, ACI J., 83, 798 (1986)

[7] 海野幸則, 合成樹脂工業, 35, 126 (1988)

[8] 官永晴治, 化學經濟, 33, 14 (1986)

[9] Fowler DW, Int. Cong. Polym. Concrete, 8, 13 (1995)

[10] Paturoev VV, Trambovetsky VP, Int. Cong. Polym. Concrete, 8, 451 (1995)

[11] Ohama Y, Demura M, Komiyama M, J. Soc. Mater. Sci., 29, 266 (1980)

[12] Mani P, Gupta AK, Krishnamoorthy S, Int. J. Adhesion Adhesives, 7, 157 (1987)

[13] Ohama Y, コソクリ-ト工學, 26, 70 (1988)

[14] 小林恒己, 藤田晃弘, 鋪裝, 21, 9 (1986)

[15] Ohama Y, コソクリ-ト工學, 28, 5 (1990)

[16] Kobaashi K, Ito T, Int. Cong. Polym. Concrete, 1, 236 (1976)

[17] Ohama Y, ポリマ-ダイヅェスト, 35, 47 (1983)

[18] Ohama Y, 材料, 36, 679 (1987)