화학공학소재연구정보센터
Journal of Chemical Physics, Vol.106, No.8, 3358-3364, 1997
Statistical-Mechanics of a Fluid in Contact with a Curved Wall
Formal expressions are derived for the surface tension of a fluid in contact with a hard spherical wall or a cavity. A method is provided for expansions in powers of curvature and applied to the first correction. Four contributions are found, one of them of the form due to Tolman.