화학공학소재연구정보센터
Journal of Chemical Physics, Vol.106, No.4, 1463-1466, 1997
Equal Reaction-Rates for All Recombination Pathways
Formal collision theory indicates that the absolute termolecular recombination reaction rate can be expressed in a form associated either with direct or indirect mechanisms for the recombination. Moreover, the same exact rate constant can be calculated using either of the four mechanisms. These results are to be contrasted to the rate constants standardly calculated by approximate methods.