Oxy-fuel power plants are among the currently known major carbon capture and storage (CCS) technologies those which produce the lowest carbon dioxide (CO2) purity CO2-stream. As a consequence, the oxy-fuel technology has the highest requirement towards CO2 purification. In the current paper two different purification processes are modeled in Aspen Plus (TM) based on a Peng-Robinson property method with k(ij) mixing coefficients. Both separation processes are based on phase separation technique. The first one is equipped with two flash columns and the second one includes a distillation column. Both plants require a dehydration plant for water removal. For each process the impact of main design parameters on performance features such as specific power requirement, specific cooling duty, separation efficiency and CO2 purity are analyzed, including variations in flue gas composition, plant load and kij mixing parameters. The results were compared to a conventional 5-stage CO2 compressor. (C) 2011 Elsevier Ltd. All rights reserved.