Journal of Chemical Physics, Vol.105, No.15, 6263-6269, 1996
Classical Trajectory and Adiabatic Channel Study of the Transition from Adiabatic to Sudden Capture Dynamics .1. Ion-Dipole Capture
Classical trajectory calculations of ion-permanent+induced dipole capture processes are performed over very wide ranges of conditions. The results are represented in a simple, two-parametric analytical form of high precision. The transition from adiabatic to nonadiabatic dynamics is expressed in terms of the Massey parameter. In the adiabatic range, perfect agreement (better than 0.4%) of the derived thermal capture rate constants from classical trajectories and results from accurate statistical adiabatic channel (SACM) calculations is obtained.
Keywords:RATE CONSTANTS;UNIMOLECULAR PROCESSES;MOLECULE COLLISIONS;LOW-TEMPERATURES;MODEL;ANISOTROPY;ATOM