The potential for chemical reduction of hexavalent chromium Cr(VI) in contaminated water and formation of a stable precipitate by Zero Valent Iron (ZVI) anode electrolysis is evaluated in a separated electrode system. Oxidation of iron electrodes produces ferrous ions, causing the development of a reducing environment in the anolyte, chemical reduction of Cr(VI) to Cr(III) and formation of stable iron-chromium precipitates. Cr(VI) transformation rates are dependent on the applied electric current density. Increasing the electric current increases the transformation rates; however, the process is more efficient under lower volumetric current density (for example 1.5 mA L-1 in this study). The transformation follows a zero order rate that is dependent on the electric current density. Cr(VI) transformation occurs in the anolyte when the electrodes are separated as well as when the electrolytes (anolyte/catholyte) are mixed, as used in electrocoagulation. The study shows that the transformation occurs in the anolyte as a result of ferrous ion formation and the product is a stable Fe15Cr5(OH)(60) precipitate. (c) 2012 Elsevier Ltd. All rights reserved.