화학공학소재연구정보센터
Electrochimica Acta, Vol.66, 52-60, 2012
Effect of probe tip inclination on the response of the Scanning Vibrating Electrode Technique to an idealised pit-like feature
The paper outlines details of a mathematical model and a series of experiments performed to evaluate the extent to which SVET response artefacts are generated when scanning non-planar surfaces. This work establishes guidelines for SVET use and the potential issues that must be taken into account when using SVET to examine the corrosion behaviour of non-planar specimens. Results from the mathematical model indicates that response artefacts will be minimal until the probe/sample angle exceeds 30 degrees off perpendicular: a finding validated by the experimental and literature data. (C) 2012 Elsevier Ltd. All rights reserved.