폴리우레탄 폼을 이용한 친유성 유체의 흡착

채주병; 김병규; 신영조

Journal of the Korean Industrial and Engineering Chemistry, Vol.9, No.5, 648-653, October, 1998

Export Citation

폴리우레탄 폼을 이용한 친유성 유체의 흡착

Adsorption of Hydrophobic Fluid by Polyurethane Foam

채주병, 김병규, 신영조

초록

본 연구에서는 폴리우레탄 폼의 셀 내부구조 및 크기가 친유성 유체의 흡유능에 미치는 영향을 체계적으로 연구하였다. 우선 다양한 분자량의 폴리올 (GP-1000, GP-3000, GP-4000, GP-5000)을 이용하여 폴리우레탄 폼을 제조하여 그 기본적인 물성을 조사하였다. 폴리올의 분자량이 증가함에 따라 셀 크기가 감소하고 흡유량이 2000% 이상 증가하였다. Surfactant 량이 증가하고 흡착되는 유체의 점도가 증가함에 따라 흡유량이 현저하게 감소함을 알 수가 있었다. 또한 폴리올의 분자량이 증가함에 따라 표면강도가 상승하였는데 이는 분자량 증가에 따른 유체점도의 상승이 폼밀도를 증대시킨데 기인한 것으로 해석할 수 있었다. 폼생성시 교반속도가 증가하여도 밀도가 증가하였다.

This study examines the effects of cell size and structure on the oil adsorption by polyurethane (PU) foam. A series of oil-adsorptive PU foam has been prepared, using various molecular weight of polyether polyol (GP-1000, GP-3000, GP-4000, GP-5000), together with TDI-80, water and additives. It was found that the cell size of PU foam decreased with increasing the agitation speed and surfactant content. Oil-adsorption of PU foam increased over 2000% with the increase of molecular weight of polyol and with the decrease of cell size. Increase in the surfactant content and the viscosity of adsorbed oil also give a remarkable decrease in oil adsorption.

Keywords:Polyurethane;Foam;Oil-adsorption;Cell Size Effect

[References]

Charles W, U.S. Patent, 5,407,575 (1995)
Thomas IB, U.S. Patent, 5,391,415 (1995)
Enkiri F, Hulen C, Legault-Demare J, Appl. Microbiol., 44, 539 (1995)
Clark NO, Blackman M, Trans. Faraday Soc., 44, 1 (1948)
Shaw DJ, "Introduction to collied and surface chemistry," 4th Ed, p. 70, ed by Butterworth-Heinemann, London, England (1992)
Brrow GM, "Physical Chemistry," 5th Ed, p. 802, MaGraw-Hill, New York (1988)
한국폴리올 주식회사, "Polyurethane Foam," p. 59 (1996)
Woods G, "The ICI Polyurethane Book," p. 80, ed. by R. Genge., etherlands (1987)
Klempher D, Frisch KC, "Handbook of Polymeric Foams and Foam Technology," ed by PTI, p. 26, Detroit, Michigan (1995)
Woods G, "The ICI Polyurethane Book," p. 81, ed. by R. Genge, Netherlands (1987)
Klempher D, Frisch KC, "Handbook of Polymeric Foams and Foam Technology," ed by PTI, p. 62, Detroit, Michigan (1995)
Kanner B, Prokai B, Adv. Urethane Sci. Technol., 2, 221 (1973)
Rossmy G, Lidy W, Shator H, J. Cell. Plast., 13, 276 (1977)
Kollmeier HJ, Burkhart G, Kleitsch J, J. Cell. Plast., 20, 410 (1984)
Burkhart G, Kollmeier HJ, Schlosen HH, J. Cell. Plast., 20, 37 (1984)
Myers D, "Surface, Interface and Colloids: Principles and Applications," pp. 103-104, VCH, New York (1991)

[Referenced By]

[1] Charles W, U.S. Patent, 5,407,575 (1995)

[2] Thomas IB, U.S. Patent, 5,391,415 (1995)

[3] Enkiri F, Hulen C, Legault-Demare J, Appl. Microbiol., 44, 539 (1995)

[4] Clark NO, Blackman M, Trans. Faraday Soc., 44, 1 (1948)

[5] Shaw DJ, "Introduction to collied and surface chemistry," 4th Ed, p. 70, ed by Butterworth-Heinemann, London, England (1992)

[6] Brrow GM, "Physical Chemistry," 5th Ed, p. 802, MaGraw-Hill, New York (1988)

[7] 한국폴리올 주식회사, "Polyurethane Foam," p. 59 (1996)

[8] Woods G, "The ICI Polyurethane Book," p. 80, ed. by R. Genge., etherlands (1987)

[9] Klempher D, Frisch KC, "Handbook of Polymeric Foams and Foam Technology," ed by PTI, p. 26, Detroit, Michigan (1995)

[10] Woods G, "The ICI Polyurethane Book," p. 81, ed. by R. Genge, Netherlands (1987)

[11] Klempher D, Frisch KC, "Handbook of Polymeric Foams and Foam Technology," ed by PTI, p. 62, Detroit, Michigan (1995)

[12] Kanner B, Prokai B, Adv. Urethane Sci. Technol., 2, 221 (1973)

[13] Rossmy G, Lidy W, Shator H, J. Cell. Plast., 13, 276 (1977)

[14] Kollmeier HJ, Burkhart G, Kleitsch J, J. Cell. Plast., 20, 410 (1984)

[15] Burkhart G, Kollmeier HJ, Schlosen HH, J. Cell. Plast., 20, 37 (1984)

[16] Myers D, "Surface, Interface and Colloids: Principles and Applications," pp. 103-104, VCH, New York (1991)