Journal of Chemical Physics, Vol.104, No.3, 962-966, 1996
Intermolecular Spectral Densities of Liquids - A Quantitative Comparison of Time-Domain and Frequency-Domain Techniques
Intermolecular spectral density measured by two independent experimental techniques, time-domain optical-heterodyne-detected Raman-induced-Kerr-effect spectroscopy (OHD-RIKES) and frequency-domain stimulated gain spectroscopy (SGS), for three molecular liquids (benzene, carbon disulfide, and chloroform) are compared. The agreement in the high-frequency (interaction-induced) portion of the spectrum (20-150 cm(-1)) is quantitative. The relative merits between time-domain and frequency-domain coherent light-scattering techniques are discussed.
Keywords:STIMULATED GAIN SPECTRA;OPTICAL KERR;RAMAN-SPECTROSCOPY;DYNAMICS;ACETONITRILE;SCATTERING;BENZENE;MODES;CS2