광전도성 N-불포화알킬카르바졸 유도체의 합성

정은실; 조을훈; 정평진

Journal of the Korean Industrial and Engineering Chemistry, Vol.9, No.4, 548-553, August, 1998

Export Citation

광전도성 N-불포화알킬카르바졸 유도체의 합성

Synthesis of Photoconductive N-unsaturated Alkylcarbazole Derivatives

정은실, 조을훈, 정평진

초록

N-불포화알카르바졸유도체는 카르바졸과 염화불포화알킬과의 친핵적1분자 치환반응 (S_Nl)에 의해서 합성했다. 이들의 반응은 질소분위기하상온에서 알칼리 (NaOH 또는 KOH)를 함유한 DMSO용매중 카르바졸과 염화불포알킬을 4시간에 걸쳐 행했으며, 이때 카르바졸에 대한 염화불포화알킬과의 몰비는 1:6:1이었다. 반옹물질과 반응생성물은 모두 CHN원소분석, ¹H-NMR 및 FT-IR에 의하여 측정되었다.

The N-unsaturated alkylcarbazole derivatives were synthesized by the unimolucular substitution reaction (S_N1) of carbazole with unsaturated alkyl chloride. These reactions between carbazole and unsaturated alkyl chloride were conducted in dimethyl sulfoxide (DMSO) comtaining alkali (NaOH or KOH) at room temperature for 4 hrs under nitrogen atmosphere. The mole ratios of carbazole, alkali and unsaturated alkyl chloride were 1:6:1, respectively. All of the compounds of starting materials and reaction products were characterized by CHN analysis, ¹H-NMR and FR-IR spectroscopy.

Keywords:Electroluminescence;N-allylcarbazole;N-2-methyl-2propenylcarbazole;N-2-vinyloxyethylcarbazole;N-p-vinylbenzylcarbazole

[References]

Adachi C, Tokito S, Tsutsui T, Saito S, Jpn. J. Appl. Phys., 27, L269 (1988)
Adachi C, Tokito S, Tsutsui T, Saito S, Appl. Phys. Lett., 55, 799 (1990)
Adachi C, Tokito S, Tsutsui T, Saito S, Appl. Phys. Lett., 57, 531 (1990)
Hamada Y, Adachi C, Tsutsui T, Saito S, Kido J, Nagai K, Ohashi Y, Chem. Lett., 657 (1990)
Kido J, Nagai K, Ohashi Y, Chem. Lett., 657 (1990)
Kido J, Hongawa K, Kohda M, Nagai K, Okuyama K, Jpn. J. Appl. Phys., 31, L960 (1992)
Kido J, Kohda M, Nagai K, Okuyama K, Nagai K, Appl. Phys. Lett., 61, 761 (1992)
Kido J, Guo Y, McBreen J, Nagai K, Okamoto Y, Polym. Adv. Technol., 3, 429 (1992)
Helfrich W, Schneider WG, Phys. Rev. Lett., 14, 229 (1965)
Tang CW, VanSlyke SA, Appl. Phys. Lett., 51, 913 (1987)
Adachi C, Tokito S, Tsutsui T, Saito S, Jpn. J. Appl. Phys., 27, L713 (1988)
Nobara N, Hasegawa M, Hosokawa C, Tokailin H, Kusumoto T, Chem. Lett., 139 (1990)
Adachi C, Tsutsui T, Saito S, Appl. Phys. Lett., 55(15), 1489 (1989)

[Referenced By]

[1] Adachi C, Tokito S, Tsutsui T, Saito S, Jpn. J. Appl. Phys., 27, L269 (1988)

[2] Adachi C, Tokito S, Tsutsui T, Saito S, Appl. Phys. Lett., 55, 799 (1990)

[3] Adachi C, Tokito S, Tsutsui T, Saito S, Appl. Phys. Lett., 57, 531 (1990)

[4] Hamada Y, Adachi C, Tsutsui T, Saito S, Kido J, Nagai K, Ohashi Y, Chem. Lett., 657 (1990)

[5] Kido J, Nagai K, Ohashi Y, Chem. Lett., 657 (1990)

[6] Kido J, Hongawa K, Kohda M, Nagai K, Okuyama K, Jpn. J. Appl. Phys., 31, L960 (1992)

[7] Kido J, Kohda M, Nagai K, Okuyama K, Nagai K, Appl. Phys. Lett., 61, 761 (1992)

[8] Kido J, Guo Y, McBreen J, Nagai K, Okamoto Y, Polym. Adv. Technol., 3, 429 (1992)

[9] Helfrich W, Schneider WG, Phys. Rev. Lett., 14, 229 (1965)

[10] Tang CW, VanSlyke SA, Appl. Phys. Lett., 51, 913 (1987)

[11] Adachi C, Tokito S, Tsutsui T, Saito S, Jpn. J. Appl. Phys., 27, L713 (1988)

[12] Nobara N, Hasegawa M, Hosokawa C, Tokailin H, Kusumoto T, Chem. Lett., 139 (1990)

[13] Adachi C, Tsutsui T, Saito S, Appl. Phys. Lett., 55(15), 1489 (1989)