Wheat straw biochars produced at 400, 600 and 800 degrees C (BC400, BC600 and BC800) were used to selectively adsorb PAHs from soil washing effluents. For soil washing effluents contained Phenanthrene (PHE), Fluoranthene (FLU), Pyrene (PYR) and Triton X-100 (TX100), biochars at 2 (for BC800) or 6 g L-1 (for BC400 and BC600) can remove 71.8-98.6% of PAHs while recover more than 87% of TX100. PAH removals increase with increasing biochar dose. However, excess biochar is detrimental to the recovery of surfactant. For a specific biochar dose, PAH removal and TX100 loss increase with increasing pyrolytic temperature. For BC400 and BC600, PAH removal follows the order of PHE > FLU > PYR, while the order is reversed with PYR > FLU > PHE for BC800. Biochars have much higher sorption affinity for PAHs than for 1'X100. It is therefore suggested that biochar is a good alternative for selective adsorption of PAHs and recovery of 1'X100 in soil washing process. (C) 2014 Elsevier Ltd. All rights reserved.