Bioresource Technology, Vol.146, 472-477, 2013
Preparation and upgrading of hydrocarbon oil from deoxy-liquefaction of oil crop
Deoxy-liquefaction of cotton seed in husk was carried out to produce hydrocarbon oil at different temperatures (400-500 degrees C). Results indicated that at 450 degrees C, the obtained oil had a maximum alkanes value of 49.58% with a low oxygen content (1.4%) resulting in the increase of HHV (43.8 MJ kg(-1)), whereas the oil contained considerable nitrogenous compounds. In the presence of gamma-Al2O3-CuO catalyst, at 450 degrees C nitrogen content in the oil dropped 20%, exhibiting the activity of catalysis for denitrification, when the content of alkanes rose to 54.91%; by vacuum distillation, the oil was then separated into light/heavy fractions which showed that they both possessed rich carbon and hydrogen with low oxygen contents. The light fractions were much the same as that of gasoline, while the heavy fractions were close to diesel, which laid the foundation of further treatment and applications. (c) 2013 Elsevier Ltd. All rights reserved.