Journal of Chemical Physics, Vol.103, No.8, 3108-3111, 1995
A Molecular Theory of Flow-Alignment and Tumbling in Sheared Nematic Liquid-Crystals
A molecular theory is presented for the dynamics of small-molecule nematic liquid crystals in shear flow. The flow-alignment angle is predicted to depend on the aspect ratio of the liquid crystal molecules, as well as the second and fourth moments, P-2 and P-4 Of the distribution of molecules about the nematic director. This theory also predicts a transition from flow alignment to tumbling well away from any nematic-smectic-A phase transitions.