A carbon felt was used as the cathode material for the indirect electrochemical reduction of indigo in alkaline aqueous solution employing iron-triethanolamine (Fe-TEA) complex as a redox mediator. Surface structure and specific surface area of the carbon felt electrode and its electrochemical performance toward the reduction of indigo were investigated by SEM, BET, and cyclic voltammetry, respectively. Moreover, an optimization of different operating conditions for the reduction of indigo was performed with an H-cell. In particular, the dependence of current efficiency (CE) on electrolysis time was chosen to analyze the indirect electrochemical reduction mechanism of indigo. The results showed that the carbon felt, having a high specific surface area of approximately 7289 cm(2).g(-1), is an excellent electrode material for the indirect electrochemical reduction of indigo and that a moderate current density, temperature, and concentration of indigo has the most beneficial effects on the reduction process.