화학공학소재연구정보센터
Chinese Journal of Chemical Engineering, Vol.22, No.1, 120-126, 2014
Organotemplate-free Hydrothermal Synthesis of SUZ-4 Zeolite: Influence of Synthesis Conditions
Various conditions were investigated in detail for the novel organic template-free static hydrothermal synthesis of SUZ-4 zeolite in the presence of seeds. The obtained samples were characterized by XRD (X-ray diffraction), SEM (scanning electron microscope), TG (thermal gravimetric analysis), ICP (inductively coupling plasma) elemental analysis, nitrogen sorption isotherm and surface area. The results show that pure SUZ-4 zeolites with high crystallinity are obtained in a broad window of synthesis conditions: seed mass concentration 0.2% 2%, SiO2/Al2O3 molar ratio 21 25, KOH/SiO2 molar ratio 0.33 0.43, H2O/SiO2 molar ratio 7.14-38.1, aging time 24 h, crystallization temperature 160 degrees C, and crystallization time 6-10 d. Also, crystallinity and size of the rod-like SUZ-4 zeolite crystals are found to alter with the conditions.