The relation between the interface structure and the exchange bias was studied in the epitaxial CoO/Fe(0 0 1) bilayers that were grown on MgO(0 0 1) using molecular beam epitaxy. Three samples with different interface structures were prepared. The CoO/Fe bilayer, which was prepared using the reactive evaporation of CoO, served as the reference sample. In the other two samples, the CoO/Fe interfaces were modified prior to the CoO growth using either (i) the deposition of a 2 angstrom thick Co layer or (ii) an exposure to molecular oxygen, which resulted in under- and over-oxidized CoO/Fe interfaces, respectively. The actual structures of the resulting interfaces were revealed using conversion electron Mossbauer spectroscopy. For each sample, an iron oxide was found at the interface, and its amount depended on the sample preparation recipe. The exchange bias effect (EB), as a function of the temperature, was experimentally studied in detail using VSM magnetometry. The coercivity showed a distinct peak near the blocking temperature for all samples; however, the peak's location and its width were diverse. The obtained EB values depended on the interface structure. The largest hysteresis loop shift (H-EB = 180 Oe at 4K) was obtained for the sample with the thickest interfacial iron oxide layer. (C) 2014 Elsevier B.V. All rights reserved.