Novel ZnO/SnO2 core-shell nanoneedle arrays were developed with a two-step synthesis strategy. The strategy combines two processes: a hydrothermal synthesis of a ZnO nanoneedle array and a coating of a SnO2 layer on the surface of the ZnO nanoneedle. The addition of F- to the hydrothermal reaction solution played an important role in the formation of the ZnO nanoneedle array. The ZnO/SnO2 core-shell structure was successfully achieved after depositing a thin SnO2 layer on the ZnO nanoneedle by dip-coating. Dye-sensitized solar cells (DSSCs) based on ZnO/SnO2 core-shell nanoneedle arrays were assembled, and a high conversion efficiency (eta) of around 4.71% was obtained at 0.9 suns. This can be attributed to the advantages of the core-shell structure. On the one hand, it affords a larger surface area for a more dye loading and light harvesting, which result in enhancing the photocurrent of the DSSC. On the other hand, the core/shell structure passivates nanoneedle surface defects for suppressing the recombination, which leads to the increase of the open-circuit voltage. Accordingly, the enhanced photocurrent and open-circuit voltage have led to a prominent increase in the photovoltaic efficiency of around 4.71%, which is much higher than that of an ordinary ZnO nanoneedle array-based DSSC. (C) 2013 Elsevier B.V. All rights reserved.