In this study, wood-plastic plywood was fabricated with high density polyethylene (HDPE) film and poplar veneer by hot-pressing. To improve the interfacial adhesion between the wood veneer and HDPE film, silane A-171 (vinyltrimethoxysilane) was used to treat the surface of poplar veneer by spraying. The effects of silane agent on the veneer surface properties as well as the physical-mechanical performance of wood-plastic plywood were evaluated. The adsorption of several prehydrolyzed alkoxysilanes onto the veneer surface and the existence of a covalent bonding between the wood veneer and silane agent were confirmed using FTIR, XPS and contact angle. Silane surface treatment resulted in enhancement of shear strength and water resistance. When one layer HDPE film was used as adhesive, it caused 293.2% increase in shear strength, 34.6% and 40.8% reduction in water absorption and thickness swelling, respectively. In addition, the wood failure also increased from 5% to 100% due to the silane modification. Dynamic mechanical analysis (DMA) results showed that treated plywood have higher storage modulus, lower tan delta peak value and lagged temperature for tan delta peak value with respect to untreated plywood. Experimental results of interfacial morphology by SEM further revealed better interaction between silane A-171 treated veneer and HDPE film. (C) 2013 Elsevier B. V. All rights reserved.