EO, PO가 부가된 도데실 에테르 황산화물의 합성

유영창; 노승호; 주명종; 남기대

Journal of the Korean Industrial and Engineering Chemistry, Vol.7, No.2, 289-298, April, 1996

Export Citation

EO, PO가 부가된 도데실 에테르 황산화물의 합성

Synthesis of Dodecyl Ether Sulfates Containing Various Ethylene Oxide and Isopropylene Oxide

유영창, 노승호, 주명종, 남기대

초록

Dodecanol에 ethylene oxide(EO)와 isopropylene oxide(PO)를 각각 5, 10몰 씩 부가하고, EO 부가물에는 PO를 PO 부가물에는 EO를 또 다시 5, 10몰 씩 부가시킨 다음 클로로술폰산으로 황산화시켜 8종의 음이온계면활성제를 합성하였다. 8종의 sodium poly(oxyethylene, oxyisopropylene) dodecyl ether sulfate에 대한 EO 및 PO의 부가를 확인하기 위하여 고성능액체크로마토그래피, 프로톤핵자기공명스펙트럼, 히드록시기값, 적외선스펙트럼을 사용하였다. 그리고 황산화를 확인하기 위하여 스펙트라와 Epton법을 이용하여 EO 및 PO 분자수를 확인하였다. 이 결과 황산화 반응의 최종 생성물의 수율은 90∼96%로써 비교적 높게 얻을 수 있었다.

Eight kinds of poly(oxyethylene, oxyisopropylene) dodecyl ethers were synthesized by adding ethylene oxide and isopropylene oxide with each 5 and 10 moles alternatively on dodecanol. The addition of EO and PO for eight kinds of sodium poly(oxyethylene, oxyisopropylene) dodecyl ether sulfates was identified with HPLC, ¹H NMR, hydroxy value, and IR spectrum. In order to verify the sulfation the number of EO and PO molecules was obtained by spectra and Epton method. The yields of products sulfated by chlorosulfonic acid were 90∼96% .

[References]

산업기술정보원, 계면활성제의 기술 현황과 응용 (1993)
Schick MJ, Fowkes FK, Surfactant Science Series No. 1, Nonionic Surfactant, Marcel Dekker, Inc., New York, U.S.A. (1966)
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Nam KD, Jeong NH, No SH, J. Korean Oil Chem. Soc., 6, 45 (1989)
Knaggs EA, Nussbaum ML, U.S. Patent, 3,544,613 (1970)
Cowie JMG, Sirianni AF, J. Am. Oil Chem. Soc., 43, 572 (1966)
Weimer DR, Cooper DE, J. Am. Oil Chem. Soc., 43, 440 (1966)
Weil JK, Stirton AJ, Barr EA, J. Am. Oil Chem. Soc., 43, 157 (1966)
Naylor CG, J. Am. Oil Chem. Soc., 63, 1201 (1986)
Sosis P, Dringoli LJ, J. Am. Oil Chem. Soc., 47, 229 (1970)
보건사회부, 화장품원료기준, 422 (1986)
보건사회부, 화장품원료기준, 435 (1986)
Jeong NH, The Synthesis and Surface Active Properties of Anionic Oligomer Surfactant with α-Sulfoalkanoic acid, 충북대 박사학위논문, 17 (1992)
McCoy RN, Bullock AB, J. Am. Oil Chem. Soc., 46, 289 (1969)
Epton SR, Nature, 160, 795 (1947)
Gildenberg L, Trowbridge JR, J. Am. Oil Chem. Soc., 42, 69 (1965)

[Referenced By]

[1] 산업기술정보원, 계면활성제의 기술 현황과 응용 (1993)

[2] Schick MJ, Fowkes FK, Surfactant Science Series No. 1, Nonionic Surfactant, Marcel Dekker, Inc., New York, U.S.A. (1966)

[3] Bistiline RG, Noble WR, Weil JK, Linfield WM, J. Am. Oil Chem. Soc., 49, 63 (1972)

[4] Nam KD, Jeong NH, No SH, J. Korean Oil Chem. Soc., 6, 45 (1989)

[5] Knaggs EA, Nussbaum ML, U.S. Patent, 3,544,613 (1970)

[6] Cowie JMG, Sirianni AF, J. Am. Oil Chem. Soc., 43, 572 (1966)

[7] Weimer DR, Cooper DE, J. Am. Oil Chem. Soc., 43, 440 (1966)

[8] Weil JK, Stirton AJ, Barr EA, J. Am. Oil Chem. Soc., 43, 157 (1966)

[9] Naylor CG, J. Am. Oil Chem. Soc., 63, 1201 (1986)

[10] Sosis P, Dringoli LJ, J. Am. Oil Chem. Soc., 47, 229 (1970)

[11] 보건사회부, 화장품원료기준, 422 (1986)

[12] 보건사회부, 화장품원료기준, 435 (1986)

[13] Jeong NH, The Synthesis and Surface Active Properties of Anionic Oligomer Surfactant with α-Sulfoalkanoic acid, 충북대 박사학위논문, 17 (1992)

[14] McCoy RN, Bullock AB, J. Am. Oil Chem. Soc., 46, 289 (1969)

[15] Epton SR, Nature, 160, 795 (1947)

[16] Gildenberg L, Trowbridge JR, J. Am. Oil Chem. Soc., 42, 69 (1965)