아민 추출제에 의한 유기산의 반응추출(I)(유기산의 반응추출시 추출도에 미치는 추출제 및 용매의 영향에 관한 연구)

류운형; 이한섭; 유철휘; 김용렬; 강안수

Journal of the Korean Industrial and Engineering Chemistry, Vol.7, No.1, 203-213, February, 1996

Reactive Extraction of Organic Acid with Amine Extration(Ⅰ) (A Study on the Effects of Extractant and Solvent on the Degree of Extraction in Reactive Extraction of Organic Acid)

류운형, 이한섭, 유철휘, 김용렬, 강안수

초록

평형 추출장치를 사용하여 유기산의 물리추출과 반응추출에서 추출도에 미치는 추출제의 종류와 농도, 용매의 영향을 조사하였다. 사용된 유기산은 아크릴산과 메타크릴산이었고, 추출제로는 n-octylamine(OA)과 di-n-octylamine(DOA), tri-n-octylamine(TOA)및 tri-octylmetyl ammonium chloride(TOMAC ; Aliquat 336)을 사용하였다. 실험결과 반응추출에서 추출도는 물리추출의 경우보다 2∼9배 정도 증가 되었으며, 유기산의 추출도에 미치는 추출제의 영향은 OA, TOMAC, DOA 및 TOA의 순서로 추출도가 중가하였으며, 또한 추출제의 농도가 증가할수록 추출도가 증가하였다. 용매의 영향은 종래의 용매의 유전상수보다는 용해도인자에 의한 용매선택 방법이 신뢰성이 있었고, 용질과 용매의 용해도인자의 차이가 작을수록 추출도가 증가하여 케로진, 크실렌, 클로로포롬, MIBK 및 n-BAc의 순서로 좋아졌다.

In physical and reactive extraction system using equilibrium extraction equipment, the effects of extractants, concentration of extractant, and solvent on the degree of extraction were investigated. The organic acids used were acrylic acid and metacrylic acid. Extractants were n-octylamine(OA), di-n-octylamine(DOA), tri-n-octylamine(TOA) and tri-octylmetyl ammonium chloride(TOMAC ; Aliquat 336). We found that the degree of extraction for reactive extraction was 2∼9 times than that for physical extraction and that effect of extractants on the degree of extraction of organic acid was the order of OA

[References]

Ricker NL, Michaels JM, King CJ, J. Separ. Proc. Technol., 1, 36 (1979)
Hampe MJ, Chem. Ing. Tech., 57, 669 (1985)
Kiezyk PR, Mackay D, Can. J. Chem. Eng., 51, 741 (1973)
Hildebrand JH, Scott RL, "Regular Solutions," Prentice-Hall, Englewood (1962)
Hoy KL, J. Paint Technol., 42, 76 (1970)
Hansen CM, Ind. Eng. Chem. Prod. Res. Dev., 8, 2 (1969)
Tamada JA, Kertes AS, King CJ, Ind. Eng. Chem. Res., 29, 1319 (1990)
Sierkeirski S, J. Inorg. Nucl. Chem., 24, 205 (1962)
Kertes AS, J. Inorg. Nucl. Chem., 27, 209 (1965)
Freiser H, Anal. Chem., 41, 1354 (1969)
Wingefors S, Acta Chem. Scandinavica, A34, 297 (1980)
Brandrup J, Immergut EH, "Polymer Handbook," John Wiley & Sons, New York (1989)
Sumitomo Chem. Co. Ltd., DE Patent, 2161525 (1971)
Matsumura H, Otani M, Murakami F, Japan Patent, 56016438 (1979)
Daicel Chem. Ind. Ltd., Japan Patent, 57095948 (1980)
Campbell FT, Pfefferkorn R, Rounsaville JF, "Ullmann's Encyclopedia of Industrial Chemistry," A1, 161, VCH Co., 5th/Ed., New York (1985)
Elvers B, Hawkins S, Schulz G, "Ullmann's Encyclopedia of Industrial Chemistry," A16, 441, VCH Co., 5th/Ed., New York (1990)
Barton AFM, "CRC Handbook of Solubility Parameters and Other Cohesion Parameters," CRC Press, Inc., Boca Raton, Florida (1983)
Lo TC, Baird MHI, Hanson C, "Handbook of Solvent Extraction," John Wiley & Sons, New York (1983)
Handojo L, "Trennung von Asparaginsaure und Arginin mittels Reaktive - extraktion," Dissertation, Hannover University, Hannover (1988)
Lee HS, Kang AS, J. Korean Ind. Eng. Chem., 5(1), 90 (1994)
Burrel H, J. Paint Technol., 40, 197 (1968)
Lambourne R, "Paint and Surface Coating: Theory and Practice," John Wiley & Sons, New York (1987)
Hildebrand JH, Scott RL, "The Solubility of Non-Electrolytes," Rheinhold Pub. Co., New York (1950)
Prausnitz JM, "Molecular Thermodynamics of Fluid Phase Equilibria," 269, Prentice-Hall, Inc. Englewood Cliffs, N.J. (1969)
Kojima I, Yoshida M, Tanaka M, J. Inorg. Nucl. Chem., 32, 987 (1970)
Ricker NL, Pittman EF, King CJ, J. Sep. Proc. Technol., 1, 23 (1980)
Crowley JD, Teague GS, Lowe JW, J. Paint Technol., 39, 19 (1967)
Gardon JL, J. Paint Technol., 38, 43 (1966)

[Referenced By]

[1] Ricker NL, Michaels JM, King CJ, J. Separ. Proc. Technol., 1, 36 (1979)

[2] Hampe MJ, Chem. Ing. Tech., 57, 669 (1985)

[3] Kiezyk PR, Mackay D, Can. J. Chem. Eng., 51, 741 (1973)

[4] Hildebrand JH, Scott RL, "Regular Solutions," Prentice-Hall, Englewood (1962)

[5] Hoy KL, J. Paint Technol., 42, 76 (1970)

[6] Hansen CM, Ind. Eng. Chem. Prod. Res. Dev., 8, 2 (1969)

[7] Tamada JA, Kertes AS, King CJ, Ind. Eng. Chem. Res., 29, 1319 (1990)

[8] Sierkeirski S, J. Inorg. Nucl. Chem., 24, 205 (1962)

[9] Kertes AS, J. Inorg. Nucl. Chem., 27, 209 (1965)

[10] Freiser H, Anal. Chem., 41, 1354 (1969)

[11] Wingefors S, Acta Chem. Scandinavica, A34, 297 (1980)

[12] Brandrup J, Immergut EH, "Polymer Handbook," John Wiley & Sons, New York (1989)

[13] Sumitomo Chem. Co. Ltd., DE Patent, 2161525 (1971)

[14] Matsumura H, Otani M, Murakami F, Japan Patent, 56016438 (1979)

[15] Daicel Chem. Ind. Ltd., Japan Patent, 57095948 (1980)

[16] Campbell FT, Pfefferkorn R, Rounsaville JF, "Ullmann's Encyclopedia of Industrial Chemistry," A1, 161, VCH Co., 5th/Ed., New York (1985)

[17] Elvers B, Hawkins S, Schulz G, "Ullmann's Encyclopedia of Industrial Chemistry," A16, 441, VCH Co., 5th/Ed., New York (1990)

[18] Barton AFM, "CRC Handbook of Solubility Parameters and Other Cohesion Parameters," CRC Press, Inc., Boca Raton, Florida (1983)

[19] Lo TC, Baird MHI, Hanson C, "Handbook of Solvent Extraction," John Wiley & Sons, New York (1983)

[20] Handojo L, "Trennung von Asparaginsaure und Arginin mittels Reaktive - extraktion," Dissertation, Hannover University, Hannover (1988)

[21] Lee HS, Kang AS, J. Korean Ind. Eng. Chem., 5(1), 90 (1994)

[22] Burrel H, J. Paint Technol., 40, 197 (1968)

[23] Lambourne R, "Paint and Surface Coating: Theory and Practice," John Wiley & Sons, New York (1987)

[24] Hildebrand JH, Scott RL, "The Solubility of Non-Electrolytes," Rheinhold Pub. Co., New York (1950)

[25] Prausnitz JM, "Molecular Thermodynamics of Fluid Phase Equilibria," 269, Prentice-Hall, Inc. Englewood Cliffs, N.J. (1969)

[26] Kojima I, Yoshida M, Tanaka M, J. Inorg. Nucl. Chem., 32, 987 (1970)

[27] Ricker NL, Pittman EF, King CJ, J. Sep. Proc. Technol., 1, 23 (1980)

[28] Crowley JD, Teague GS, Lowe JW, J. Paint Technol., 39, 19 (1967)

[29] Gardon JL, J. Paint Technol., 38, 43 (1966)