화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.31, No.8, 1470-1479, August, 2014
DOI10.1007/s11814-014-0086-3  Export Citation
New carbon composite adsorbents for the removal of textile dyes from aqueous solutions: Kinetic, equilibrium, and thermodynamic studies
Davis Castro dos Santos1, Matthew Ayorinde Adebayo2, 3, Simone de Fátima Pinheiro Pereira1, Lizie Daniela Tentler Prola2, Renato Cataluña2, Eder Cláudio Lima1, †, Caroline Saucier2, Caline Rodrigues Gally2, and Fernando Machado Machado4
  • 1Institute of Exact and Natural Sciences, Federal University of Para, UFPA, Belem, PA, Brazil
  • 2Institute of Chemistry, Federal University of Rio Grande do Sul, UFRGS, Av. Bento Gonçalves 9500, Postal Box 15003, ZIP 91501-970, Porto Alegre, RS, Brazil
  • 3Department of Chemical Sciences, Ajayi Crowther University, PMB 1066, Oyo, Oyo State, Nigeria
  • 4Universitary Center Franciscano, UNIFRA, R. dos Andradas 1614, ZIP 97010-032, Santa Maria, RS, Brazil
E-mail:
New carbon composite materials were prepared by pyrolysis of mixture of coffee wastes and red mud at 700 ℃ with the inorganic : organic ratios of 1.9 (CC-1.9) and 2.2 (CC-2.2). These adsorbents were used to remove reactive orange 16 (RO-16) and reactive red 120 (RR-120) textile dyes from aqueous solution. The CC-1.9 and CC-2.2 materials were characterized using Fourier transform infrared spectroscopy, Nitrogen adsorption/desorption curves, scanning electron Microscopy and X-ray diffraction. The kinetic of adsorption data was fitted by general order kinetic model. A three-parameter isotherm model, Liu isotherm model, gave the best fit of the equilibrium data (298 to 323 K). The maximum amounts of dyes removed at 323 K were 144.8 (CC-1.9) and 139.5 mg g-1 (CC-2.2) for RO-16 dye and 95.76 (CC-1.9) and 93.80 mg g-1 (CC-2.2) for RR-120 dye. Two simulated dyehouse effluents were used to investigate the application of the adsorbents for effluent treatment.
Keywords:Adsorption;Aqueous Effluents;Carbon Composite;General Order Kinetic Model;Pyrolysis
  1. Hessel C, Allegre C, Maisseu M, Charbit F, Moulin P, J. Environ. Manage., 83, 171 (2007)
  2. Allegre C, Moulin P, Maisseu M, Charbit F, J. Membr. Sci., 269(1-2), 15 (2006)
  3. Cardoso NF, Lima EC, Royer B, Bach MV, Dotto GL, Pinto LAA, Calvete T, J. Hazard. Mater., 241-242, 146 (2012)
  4. da Silva LG, Ruggiero R, Gontijo PD, Pinto RB, Royer B, Lima EC, Fernandes THM, Calvete T, Chem. Eng. J., 168(2), 620 (2011)
  5. Brookstein DS, Dermatol. Clin., 27, 309 (2009)
  6. de Lima ROA, Bazo AP, Salvadori DMF, Rech CM, Oliveira DP, Umbuzeiro GA, Mutat. Res. Genet. Toxicol. Environ. Mutagen., 626, 53 (2007)
  7. Carneiro PA, Umbuzeiro GA, Oliveira DP, Zanoni MVB, J. Hazard. Mater., 174(1-3), 694 (2010)
  8. Oplatowska M, Donnelly RF, Majithiya RJ, Kennedy DG, Elliott CT, Food Chem. Toxicol., 49, 1870 (2011)
  9. Ali H, Water Air Soil Pollut., 213, 251 (2010)
  10. Alijani S, Moghaddam AZ, Vaez M, Towfighi J, Korean J. Chem. Eng., 30(10), 1855 (2013)
  11. Royer B, Cardoso NF, Lima EC, Macedo TR, Airoldi C, J. Hazard. Mater., 181(1-3), 366 (2010)
  12. Royer B, Cardoso NF, Lima EC, Ruiz VSO, Macedo TR, Airoldi C, J. Colloid Interface Sci., 336(2), 398 (2009)
  13. de Menezes EW, Lima EC, Royer B, de Souza FE, dos Santos BD, Gregorio JR, Costa TMH, Gushikem Y, Benvenutti EV, J. Colloid Interface Sci., 378, 10 (2012)
  14. Prola LDT, Acayanka E, Lima EC, Umpierres CS, Vaghetti JCP, Santos WO, Laminsi S, Njifon PT, Ind. Crop. Prod., 46, 328 (2013)
  15. Dotto GL, Lima EC, Pinto LAA, Bioresour. Technol., 103(1), 123 (2012)
  16. Nethaji S, Sivasamy A, Mandal AB, Int. J. Environ. Sci. Technol., 10, 231 (2013)
  17. Sharma P, Kaur H, Sharma M, Sahore V, Environ. Monit. Assess., 183, 151 (2011)
  18. Prola LDT, Machado FM, Bergmann CP, de Souza FE, Gally CR, Lima EC, Adebayo MA, Dias SLP, Calvete T, J. Environ. Manage., 130, 166 (2013)
  19. Cardoso NF, Lima EC, Pinto IS, Amavisca CV, Royer B, Pinto RB, Alencar WS, Pereira SFP, J. Environ. Manage., 92, 1237 (2011)
  20. Prola LDT, Acayanka E, Lima EC, Bestetti C, Santos WO, Pavan FA, Dias SLP, Tarley CRT, Desalin. Water Treat., 51, 4582 (2013)
  21. Machado FM, Bergmann CP, Fernandes THM, Lima EC, Royer B, Calvete T, Fagan SB, J. Hazard. Mater., 192(3), 1122 (2011)
  22. Alencar WS, Lima EC, Royer B, dos Santos BD, Calvete T, da Silva EA, Alves CN, Sep. Sci. Technol., 47(3), 513 (2012)
  23. Calvete T, Lima EC, Cardoso NF, Vaghetti JCP, Dias SLP, Pavan FA, J. Environ. Manage., 91, 1695 (2010)
  24. Marsh H, Reinoso FR, Activated Carbon, Elsevier, Amsterdam (2006).
  25. Mitome T, Uchida Y, Egashira Y, Hayashi K, Nishiura A, Nishiyama N, Colloids Surf. A: Physicochem. Eng. Asp., 424, 89 (2013)
  26. Sahin O, Saka C, Bioresour. Technol., 136, 163 (2013)
  27. Kong JJ, Yue QY, Huang LH, Gao Y, Sun YY, Gao BY, Li Q, Wang Y, Chem. Eng. J., 221, 62 (2013)
  28. Wang Q, Luan ZK, Wei N, Li J, Liu CX, J. Hazard. Mater., 170(2-3), 690 (2009)
  29. da Silva-Filho EB, Alves MCM, da Motta M, Oliveira EHC, Brander W, Quim. Nova, 31, 985 (2008)
  30. de Souza KC, Antunes MLP, Couperthwaite SJ, da Conceicao FT, de Barros TR, Frost R, J. Colloid Interface Sci., 396, 210 (2013)
  31. Tor A, Cengeloglu Y, J. Hazard. Mater., 138(2), 409 (2006)
  32. Martires RAC, Sumario Mineral 2012. Departamento Nacional de Producao Mineral. Brasil (2012).
  33. Tully PS, Sulfonic acids. Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley and Sons, New Jersey (2000).
  34. Jacques RA, Lima EC, Dias SLR, Mazzocato AC, Pavan FA, Sep. Purif. Technol., 57(1), 193 (2007)
  35. Jacques RA, Bernardi R, Caovila M, Lima EC, Pavan FA, Vaghetti JCP, Airoldi C, Sep. Sci. Technol., 42(3), 591 (2007)
  36. Vaghetti JCP, Zat M, Bentes KRS, Ferreira LS, Benvenutti EV, Lima EC, J. Anal. Atom. Spectrom., 18, 376 (2003)
  37. Barbosa F, Krug FJ, Lima EC, Spectroc. Acta Pt. B-Atom. Spectr., 54, 1155 (1999)
  38. Lima EC, Brasil JL, Santos AHDP, Anal. Chim. Acta, 484, 233 (2003)
  39. Lima EC, Krug FJ, Nobrega JA, Nogueira ARA, Talanta, 47, 613 (1998)
  40. Lima EC, Fenga PG, Romero JR, de Giovani WF, Polyhedron, 17, 313 (1998)
  41. Liu Y, Liu Y, Sep. Purif. Technol., 61(3), 229 (2008)
  42. Liu Y, Shen L, Biochem. Eng. J., 38, 390 (2008)
  43. Ho YS, J. Hazard. Mater., 136(3), 681 (2006)
  44. Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civil Eng., 89, 31 (1963)
  45. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  46. Freundlich H, Phys. Chem. Soc., 40, 1361 (1906)
  47. Liu Y, Xu H, Yang SF, Tay JH, J. Biotechnol., 102, 233 (2003)
  48. El-Khaiary MI, Malash GF, Hydrometallurgy, 105, 314 (2011)
  49. Gupta VK, Nayak A, Chem. Eng. J., 180, 81 (2012)
  50. Suksabye P, Thiravetyan P, J. Environ. Manage., 102, 1 (2012)
  51. Zhang J, Ping Q, Niu M, Shi H, Li N, Appl. Clay Sci., 83-84, 12 (2013)
  52. Sun CL, Wang CS, J. Mol. Struct., 956, 38 (2010)
  53. Kyzas GZ, Lazaridis NK, Bikiaris DN, Carbohydr. Polym., 91, 198 (2013)
  54. Travlou NA, Kyzas GZ, Lazaridis NK, Deliyanni EA, Chem. Eng. J., 217, 256 (2013)