화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 2497-2509, July, 2014
DOI10.1016/j.jiec.2013.10.032  Export Citation
Carbon dioxide absorption studies using amine-functionalized ionic liquids
Yamini Sudha Sistla, and Ashok Khanna†
  • Department of Chemical Engineering, Indian Institute of Technology Kanpur, 208016, India
E-mail:
Several amine-functionalized cation ILs were successfully synthesized, characterized and tested for CO2 absorption studies. Non-functionalized ILs were studied for comparison purpose. The primary amine-ILs have shown higher CO2 solubilities both on molar basis (mol of CO2/mol of IL) and on volume basis (g of CO2/L of IL), compared to non-functionalized and tertiary-amine ILs. Besides amine-functionalization of the cation, anion of the IL has strong influence on CO2 solubility due to its contribution by physical absorption. As a result, the [TF2N]-anion amine-ILs have higher CO2 solubility than [BF4]-anion amine-ILs. Among non-amine functionalized ILs, [P(14)666][TF2N] has the highest CO2 solubility.
Keywords:Absorption;Separation;Diffusion;CO2 capture;Ionic liquid
  1. Thomas DC, Carbon Dioxide Capture for Storage in Deep Geologic Formations .Results from CO2 Capture Project. Capture and Separation of Carbon Dioxide from Combustion Sources, vol. 1, Elsevier, 2005.
  2. Alessandro DM, Smit B, Long JR, Angew. Chem., 49, 6058 (2010)
  3. Benson SM, Oldenburg C, Hoversten M, Imbus S, Carbon Dioxide Capture for Storage in Deep Geologic Formations . Results from CO2 Capture Project; Geologic Storage of Carbon Dioxide with Monitoring and Verification, vol. 2, Elsevier, 2005.
  4. Jones CW, Annu. Rev. Chem. Biomol. Eng., 2, 31 (2011)
  5. Brennecke JF, Rogers RD, Seddon KR, ACS Symp. Ser., 975 (2005)
  6. Blanchard LA, Hancu D, Beckman EJ, Brennecke JF, Nature, 399, 28 (199)
  7. Elena TC, Skinner J, David GT, J. Chem. 84 (2013), ID 4735.
  8. Wasserscheid P, Welton T, Ionic Liquids in Synthesis, vol. 1, Wiley VCH, 2008.
  9. Anthony JL, Anderson JL, Maginn EJ, Brennecke JF, J. Phys. Chem., 109, 6366 (2005)
  10. Muldoon MJ, Aki SNVK, Anderson JL, Dixon JK, Brennecke JF, J. Phys. Chem., 111(30), 9001 (2007)
  11. Anthony JL, Maginn EJ, Brennecke JF, J. Phys. Chem. B, 106(29), 7315 (2002)
  12. Anderson JL, Dixon JK, Maginn EJ, Brennecke JF, J. Phys. Chem. B, 110(31), 15059 (2006)
  13. Anderson JL, Dixon JK, Brennecke JF, Acc. Chem. Res., 40, 1208 (2007)
  14. Brennecke JF, Gurkan BE, J. Phys. Chem. Lett., 1, 3459 (2010)
  15. Finotello A, Bara JE, Narayan S, Camper D, Noble RD, J. Phys. Chem. B, 112(8), 2335 (2008)
  16. Blanchard LA, Gu ZY, Brennecke JF, J. Phys. Chem. B, 105(12), 2437 (2001)
  17. Baltus RE, Culbertson BH, Dai S, Luo HM, DePaoli DW, J. Phys. Chem. B, 108(2), 721 (2004)
  18. Zhang J, Sun J, Zhang X, Zhao Y, Zhang S, Greenhouse Gas Sci. Technol., 1, 142 (2011)
  19. Deng D, Wang Q, Cui Y, Ai N, Chem. Bull., 74(8), 701 (2011)
  20. Li QW, Zhao Y, Wang LD, Adv. Mater. Res., 347-353, 116 (2011)
  21. Mattedi S, Carvalho PJ, Coutinho JAP, Alvarez VH, Iglesias M, J. Supercrit. Fluids, 56(3), 224 (2011)
  22. Carvalho PJ, Coutinho JAP, J. Phys. Chem. Lett., 1, 774 (2010)
  23. Carvalho PJ, Alvarez VH, Marrucho IM, Aznar M, Coutinho JAP, J. Supercrit. Fluids, 52(3), 258 (2010)
  24. Aki SNVK, Mellein BR, Saurer EM, Brennecke JF, J. Phys. Chem. B, 108(52), 20355 (2004)
  25. Revelli AL, Mutelet F, Jaubert JN, J. Phys. Chem. B, 114(40), 12908 (2010)
  26. Cadena C, Anthony JL, Shah JK, Morrow TI, Brennecke JF, Maginn EJ, J. Am. Chem. Soc., 126(16), 5300 (2004)
  27. Zhang F, Fang CG, Wu YT, Wang YT, Li AM, Zhang ZB, Chem. Eng. J., 160(2), 691 (2010)
  28. Yan F, Lartey M, Damodaran K, Albenze E, Thompson RL, Kim J, Haranczyk M, Nulwala HB, Luebke DR, Smit B, Phys. Chem. Chem. Phys., 15, 3264 (2013)
  29. Sanchez LMG, Meindersma GW, de Haan AB, Chem. Eng. Res. Des., 85(A1), 31 (2007)
  30. Klamt F, Eckert W, Arlt, Annu. Rev. Chem. Biomol. Eng., 1, 101 (2010)
  31. Palomar J, Ferro VR, Torrecilla JS, Rodriguez F, Ind. Eng. Chem. Res., 46(18), 6041 (2007)
  32. Ab Manan N, Hardacre C, Jacquemin J, Rooney DW, Youngs TGA, J. Chem. Eng. Data, 54(7), 2005 (2009)
  33. Palomar J, Miquel MG, Polo A, Rodriguez F, Ind. Eng. Chem. Res., 50, 3452 (2011)
  34. Sistla YS, Khanna A, J. Chem. Eng. Data, 56(11), 4045 (2011)
  35. Sumon KZ, Henni A, Fluid Phase Equilib., 310(1-2), 39 (2011)
  36. Bhargava BL, Balasubramanian S, Chem. Phys. Lett., 444(4-6), 242 (2007)
  37. Holloczki O, Kelemen Z, Konczol L, Szieberth D, Nyulaszi L, Stark A, Kirchner B, ChemphysChem, 14, 315 (2013)
  38. Deschamps J, Gomes MFC, Padua AAH, ChemphysChem, 5, 1049 (2004)
  39. Gutowski KE, Maginn EJ, J. Am. Chem. Soc., 130(44), 14690 (2008)
  40. Privalova E, Karjalainen E, Nurmi M, Arvela PM, Eranen K, Tenhu H, Murzin DY, Mikkola JP, ChemSusChem, 6(8), 1500 (2013)
  41. Bates ED, Mayton RD, Ntai I, Davis JH, J. Am. Chem. Soc., 124(6), 926 (2002)
  42. Sharma P, Park SD, Park KT, Nam SC, Jeong SK, Yoon Y, Baek Y, Chem. Eng. J., 193-194, 267 (2012)
  43. Gurkan BE, de la Fuente JC, Mindrup EM, Ficke LE, Goodrich BF, Price EA, Schneider WF, Brennecke JF, J. Am. Chem. Soc., 132(7), 2116 (2010)
  44. Gurkan B, Goodrich BF, Mindrup EM, Ficke LE, Massel M, Seo S, Senftle TP, Wu H, Glaser MF, Shah JK, Maginn EJ, Brennecke JF, Schneider WF, J. Phys. Chem. Lett., 1, 3494 (2010)
  45. Peng H, Zhou Y, Liu J, Zhang H, Xia C, Zhou X, RSC Adv., 3, 6859 (2013)
  46. Wang Z, Zhang Q, Kuehner D, Xu X, Ivaska A, Niu L, Carbon, 46, 1687 (2008)
  47. Zhang Z, Hu S, Song J, Li W, Yang G, Han B, ChemSusChem, 2, 234 (2009)
  48. Soave G, Chem. Eng. Sci., 27, 1197 (1972)
  49. Treybal RE, Mass Transfer Operations, 3rd ed., McGraw Hill, 1980.
  50. Silverstein RM, Webster FX, Kiemle D, Spectrometric Identification of Organic Compounds, 7th ed., Wiley, 2005.
  51. Zhang S, Sun N, He X, Lu X, Zhang X, J. Phys. Chem. Ref. Data, 35(4), 1475 (2006)
  52. Khupse N, Kurolikar SR, Kumar A, Indian J. Chem., 49, 727 (2010)
  53. Schubert TJS, Ionic Liq. Today, 1 (2011)
  54. Sistla YS, Jain L, Khanna A, Sep. Purif. Technol., 97, 51 (2012)
  55. Hansen CM, Hansen Solubility Parameters, A Users Handbook, 2nd ed., CRC Press, Taylor & Francis Group, 2007.
  56. Danon A, Stair PC, Weitz E, J. Phys. Chem. C, 115, 11540 (2011)
  57. Hapiot P, Lagrost C, Chem. Rev., 108(7), 2238 (2008)
  58. Huang J, Ruther T, Aust. J. Chem., 62, 298 (2009)
  59. Scovazzo P, J. Membr. Sci., 343(1-2), 199 (2009)