화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 1532-1541, July, 2014
DOI10.1016/j.jiec.2013.07.043  Export Citation
Separation of Co(II) and Mn(II) from sulphate media via a HFSLM: Reaction flux model and experimental verification
Teerapon Pirom, Kraiwith Wongkaew, Thanaporn Wannachod, Ura Pancharoen†, and Natchanun Leepipatpiboon1, †
  • Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand
  • 1Chromatography and Separation Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Patumwan, Bangkok 10330, Thailand
E-mail:,
Separation of Co(II) and Mn(II) from sulphate media through triple HFSLM in series using D2EHPA was explored. Mn(II) was extracted preferentially over Co(II) at the pH value of 5, 100 ppm of Co(II) and Mn(II), 5% (v/v) of D2EHPA, 0.2 M HCl. The highest extraction percentage of Mn(II) was 98.14%, and Co(II) remained at 94.05% in the raffinate stream. The reaction order (n) and the reaction rate constant (kf) were found to be 1.00 and 0.0180 min^(-1), respectively. Furthermore, the reaction flux model proved to be in good agreement with the experimental data at an average deviation of 2.24%.
Keywords:Separation;Co(II);Mn(II);D2EHPA;HFSLM
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