화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Clean Technology, Vol.20, No.2, 108-115, June, 2014
Export Citation
고정화 산성 이온성 액체 촉매와 금속염화물 촉매를 이용한 셀룰로우스의 5-HMF로의 직접 전환 연구
Direct Conversion for the Production of 5-HMF from Cellulose over Immobilized Acidic Ionic Liquid Catalyst with Metal Chloride
박용범, 최재형, 임한권1, †, 우희철†
  • 부경대학교 화학공학과, 608-739 부산시 남구 신선로 365
  • 1대구가톨릭대학교 화학시스템공학과, 712-702 경북 경산시 하양읍 하양로 13-13
Yong Beom Park, Jae Hyung Choi, Han-kwon Lim1, †, and Hee-Chul Woo†
  • Department of Chemical Engineering, Pukyong National University, 365 Sinseon-ro, Nam-gu, Busan 608-739, Korea
  • 1Department of Chemical Systematic Engineering, Catholic University of Daegu, 13-13 Hayang-ro, Hayang-yep, Gyeongsan-si, Gyeongbuk 712-702, Korea
E-mail:,
초록
셀룰로우스(cellulose)를 5-히드록시메틸푸르푸랄(5-hydroxymethylfurfural, 5-HMF)로 직접 전환하기 위해 이온성 액체 용매하에서 다양한 금속염화물과 산 촉매를 비교 연구하였다. 사용한 금속염화물은 Sn(II), Zn(II), Al(III), Fe(III), Cu(II), Cr(III)를 포함한 염화물을 비교하였으며 산 촉매는 산성 이온성 액체를 고정화하여 사용하였다. 비교를 위하여 H2SO4, HCl, Amberlyst-15와 DOWEX50x8을 사용하였다. 제조한 촉매의 산도와 산 밀도 특성은 Hammett Indicator 지시약을 통하여 분석하였다. 5-HMF의 선택도 및 수율은 반응온도, 반응시간과 촉매 비를 통하여 확인하였다. 사용한 촉매들 중에서 5-HMF의 선택도는 CrCl3-6H2O와 SiO2-[ASBI]HSO4를 사용하였을 때에 가장 높게 나타났으며, 상용화 고체 산인 Amberlyst-15와 DOWEX50x8에 비하여 활성이 높다는 것을 확인할 수 있었다. 5-HMF의 선택도는 산 촉매의 산도와 반응에 사용된 촉매비에 영향이 있음을 확인할 수 있었으며, 반응 중 재수화 반응이 일어나 레불린산(levulinic acid)이 생성된다는 것을 확인하였다.
Various metal chlorides and acid catalysts in ionic liquid solvent were investigated to directly convert cellulose into 5-hydroxymethylfurfural (5-HMF). Metal chlorides containing Sn(II), Zn(II), Al(III), Fe(III), Cu(II), and Cr(III) were used and acidic ionic liquid immobilized on silica gel as an acid catalyst and commercial acid catalysts (sulfuric acid, chloric acid, Amberlyst-15, DOWEX50x8) were used for comparison studies. The acid strength and amount of acid catalysts were probed with Hammett indicator. The selectivity and yield of 5-HMF were determined with reaction temperature, reaction time and catalyst ratio. A catalyst containing CrCl3-6H2O and SiO2-[ASBI]HSO4 showed the highest selectivity and it was found that this catalyst had higher activity than commercial solid acid catalysts such as Amberlyst-15 and DOWEX50x8. The selectivity of 5-HMF appeared to be mainly dependent on the acid strength and catalyst ratio, it was found that levulinic acid was produced from 5-HMF by rehydration.
Keywords:Cellulose;5-hydroxymethylfurfural;Ionic liquid;Dehydration
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