An advanced Cr(III) selective nano-composite cation exchanger: Synthesis, characterization and sorption characteristics

Lutfullah; Mohd Rashid; Uzma Haseen; Nafisur Rahman

Journal of Industrial and Engineering Chemistry, Vol.20, No.3, 809-817, May, 2014

DOI10.1016/j.jiec.2013.06.010 Export Citation

An advanced Cr(III) selective nano-composite cation exchanger: Synthesis, characterization and sorption characteristics

Lutfullah^†, Mohd Rashid, Uzma Haseen, and Nafisur Rahman

Department of Chemistry, Aligarh Muslim University, Aligarh 202002, India

E-mail:

An organic.inorganic composite poly-o-toluidine zirconium(IV) iodosulphosalicylate has been synthesized by mixing poly-o-toluidine into the gel of zirconium(IV) iodosulphosalicylate. The physicochemical properties of the material were characterized by FTIR, X-ray, TGA-DTA, SEM, TEM and EDX analysis. The ion-exchange capacity and chemical stability were determined. The adsorption efficiency toward heavy metal ions was determined and material was found to be highly selective for Cr(III). The thermodynamics and kinetics of the sorption of Cr(III) were studied. Adsorption of Cr(III) was explained by pseudo-first order kinetic model. The analytical utility of the material was demonstrated by achieving separation of Cr(III) from other metal ions.

Keywords:Poly-o-toluidine zirconium(IV);iodosulphosalicylate;Ion-exchange capacity;Cr(III) selectivity;Pseudo first order kinetic model;Particle diffusion controlled

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[1] Liu MH, Zhang JS, Fang YC, Deng Y, Chin. J. Inst. National., 37, 283 (1998)

[2] Aravindhan R, Madhan B, Rao JR, Nair WU, Ramasami T, Environ. Sci. Technol., 38, 300 (2004)

[3] National Standards for the Peoples’s Republic of China, Effluent Standard for the Pollutants from the Leather Industry GB 3549-3583, China Standard Press, Beijing, 1983. (1983)

[4] Kabay N, Arda M, Saha B, Streat M, React. Funct. Polym., 54(1-3), 103 (2003)

[5] Inagaki S, Guan S, Fukushima Y, Ohsuna T, Terasaki O, J. Am. Chem. Soc., 121(41), 9611 (1999)

[6] Grudzien RM, Grabicka BE, Pikus S, Jaroniec M, Chem. Mater., 18, 1722 (2006)

[7] Stein A, Melde BJ, Holland BT, Blanford CF, Chem. Mater., 11, 3302 (1999)

[8] Abd El-Latif MM, El-Kady MF, J. Appl. Sci. Res., 4, 1 (2008)

[9] Sundaram CS, Meenakshi S, J. Colloid Interface Sci., 333(1), 58 (2009)

[10] Chubar NI, Kanibolotskyy VA, Strelko VV, Gallios GG, Samanidou VF, Shaposhnikova TO, Milgrandt VG, Zhuravlev IZ, Colloids Surf. A: Physicochem. Eng. Asp., 255, 55 (2005)

[11] Xianzhu X, Jiangwei S, Defeng L, Fengshou X, Chin. Sci. Bull., 49, 2449 (2004)

[12] Zhang ZT, Dai S, J. Am. Chem. Soc., 123(37), 9204 (2001)

[13] Xu X, Han Y, Zhao L, Yu Y, Li D, Ding H, Li N, Guo Y, Xiao FS, Chem. Mater., 15, 74 (2003)

[14] Mahmoud ME, Hafez OF, Osman MM, Yakout AA, Alrefaay A, J. Hazard. Mater., 176(1-3), 906 (2010)

[15] Mustafa S, Ahmad T, Naeem A, Shah KH, Waseem M, Water Air Soil Pollut., 1020, 43 (2010)

[16] Gupta VK, Singh P, Rahman N, Anal. Biochem., 381, 471 (2005)

[17] Li XG, Huang MR, Liu R, React. Funct. Polym., 62(3), 285 (2005)

[18] Rao CNR, Chemical Applications of Infrared Spectroscopy, Academic Press, New York, 1963p. 355. (1963)

[19] Silverstien RM, Webster FX, Spectrometric Identification of Organic Compounds, 6th edn., John Wiley & Sons, New Delhi, 2005p. 96. (2005)

[20] Socrates G, Infrared Characteristic Group Frequencies, John Wiley & Sons, New York, 1980, pp. 84, 145.. (1980)

[21] Varshney KG, Pandith AH, Gupta U, Langmuir, 14(26), 7353 (1998)

[22] Duval C, Inorganic Thermogravimetric Analysis, Elsevier, Amsterdam, 1963 p.315. (1963)

[23] Persson I, Pure Appl. Chem., 82, 1901 (2010)

[24] Mezenner NY, Bensmaili A, Chem. Eng. J., 147(2-3), 87 (2009)

[25] Arias F, Sen TK, Colloids Surf. A: Physicochem. Eng. Asp., 348, 100 (2009)

[26] Jaysawal A, Chadasama U, J. Sci. Ind. Res., 66, 945 (2007)

[27] Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)