The deactivation study of Co-Ru-Zr catalyst depending on supports in the dry reforming of carbon dioxide

Ji-Hye Lee; Young-Woo You; Hong-Chan Ahn; Ji-Sook Hong; Seong-Bo Kim; Tae-Sun Chang; Jeong-Kwon Suh

Journal of Industrial and Engineering Chemistry, Vol.20, No.1, 284-289, January, 2014

DOI10.1016/j.jiec.2013.03.036 Export Citation

The deactivation study of Co-Ru-Zr catalyst depending on supports in the dry reforming of carbon dioxide

Ji-Hye Lee^{1, 2}, Young-Woo You², Hong-Chan Ahn², Ji-Sook Hong², Seong-Bo Kim², Tae-Sun Chang², and Jeong-Kwon Suh^{1, 2, †}

¹Green Chemistry and Environmental Biotechnology, University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon 305-350, Republic of Korea
²Environment and Resource Process Research Center, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Yuseong-gu, Daejeon 305-600, Republic of Korea

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Carbon dioxide reforming of methane was performed over Co-Ru-Zr catalyst (0.4 wt% Ru added, calcined at 400 ℃) with different supports (SiO2, g-Al2O3 and MgO) in order to study their deactivation. The Co-Ru-Zr/γ-Al2O3 showed the highest activity at first, but severe deactivation was observed due to carbon deposition. Co-Ru-Zr/MgO exhibited low activity because of its low specific surface area. However, the high conversions could be obtained in Co-Ru-Zr/SiO2, and activity was kept almost constantly for 500 h reaction. The characteristics of the catalysts, before and after the reaction, were investigated employing BET, XRD, TPR, TGA-DTA and TEM.

Keywords:Dry reforming;Carbon deposition;Gamma-alumina;Silica;Magnesia;Support

[References]

Yokota S, Okumura K, Niwa M, Catal. Lett., 84(1-2), 131 (2002)
Stagg SM, Romeo E, Padro C, Resasco DE, J. Catal., 178(1), 137 (1998)
Pawelec B, Damyanova S, Arishtirova K, Fierro JLG, Petrov L, Appl. Catal. A: Gen., 323, 188 (2007)
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Kohn MP, Castaldi MJ, Farrauto RJ, Appl. Catal. B: Environ., 94(1-2), 125 (2010)
Nam JK, Lee JH, Song SH, Ahn HC, Chang TS, Suh JK, Kim SB, Applied Chemistry for Engineering., 23, 176 (2011)
Song SH, Lee SB, Bae JW, Prasad PSS, Jun KW, Shul YG, Catal. Lett., 129(1-2), 233 (2009)
Flego C, Carluccio L, Rizzo C, Perego C, Catalysis Communications., 2, 43 (2001)
Garcia-Dieguez M, Pieta IS, Herrera MC, Larrubia MA, Malpartida I, Alemany LJ, Catal. Today, 149(3-4), 380 (2010)
Lee HH, Song SH, Chang TS, Hong JS, Suh JK, Lee CY, Appl. Chem. Eng., 22(2), 161 (2011)
Sigl M, Bradford MCJ, Kno¨ zinger H, Vannice MA, Topics in Catalysis., 8, 211 (1999)
Bouarab R, Akdim O, Auroux A, Cherifi O, Mirodatos C, Appl. Catal. A: Gen., 264(2), 161 (2004)
Zhang YH, Xiong HF, Liew KY, Li JL, J. Mol. Catal. A-Chem., 237(1-2), 172 (2005)
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Rostrup-Nielsen JR, Hansen JHB, Journal of Catalysis., 144, 38 (1993)
Takanabe K, Nagaoka K, Nariai K, Aika K, J. Catal., 232(2), 268 (2005)
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Hou ZY, Yashima T, Catal. Lett., 89(3-4), 193 (2003)
Hong JS, Hwang JS, Jun KW, Sur JC, Lee KW, Appl. Catal. A: Gen., 218(1-2), 53 (2001)
Nurunnabi M, Murata K, Okabe K, Inaba M, Takahara I, Catalysis Communications., 8, 1531 (2007)
Zhang JG, Wang H, Dalai AK, J. Catal., 249(2), 300 (2007)
Backman LB, Rautiainen A, Krause AOI, Lindblad M, Catal. Today, 43(1-2), 11 (1998)
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Ocsachoque M, Pompeo F, Gonzalez G, Catal. Today, 172(1), 226 (2011)

[Referenced By]

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[2] Stagg SM, Romeo E, Padro C, Resasco DE, J. Catal., 178(1), 137 (1998)

[3] Pawelec B, Damyanova S, Arishtirova K, Fierro JLG, Petrov L, Appl. Catal. A: Gen., 323, 188 (2007)

[4] Garcı´a V, Ferna´ ndez JJ, Ruı´z W, Mondrago´ n F, Moreno A, Catalysis Communications., 11, 240 (2009)

[5] Hou Z, Chen P, Fang H, Zheng X, International Journal of Hydrogen Energy., 31, 555 (2006)

[6] Kohn MP, Castaldi MJ, Farrauto RJ, Appl. Catal. B: Environ., 94(1-2), 125 (2010)

[7] Nam JK, Lee JH, Song SH, Ahn HC, Chang TS, Suh JK, Kim SB, Applied Chemistry for Engineering., 23, 176 (2011)

[8] Song SH, Lee SB, Bae JW, Prasad PSS, Jun KW, Shul YG, Catal. Lett., 129(1-2), 233 (2009)

[9] Flego C, Carluccio L, Rizzo C, Perego C, Catalysis Communications., 2, 43 (2001)

[10] Garcia-Dieguez M, Pieta IS, Herrera MC, Larrubia MA, Malpartida I, Alemany LJ, Catal. Today, 149(3-4), 380 (2010)

[11] Lee HH, Song SH, Chang TS, Hong JS, Suh JK, Lee CY, Appl. Chem. Eng., 22(2), 161 (2011)

[12] Sigl M, Bradford MCJ, Kno¨ zinger H, Vannice MA, Topics in Catalysis., 8, 211 (1999)

[13] Bouarab R, Akdim O, Auroux A, Cherifi O, Mirodatos C, Appl. Catal. A: Gen., 264(2), 161 (2004)

[14] Zhang YH, Xiong HF, Liew KY, Li JL, J. Mol. Catal. A-Chem., 237(1-2), 172 (2005)

[15] Chun HJ, Seo G, Introduction of Catalyst, 4th ed., Hanrimwon Publishing Co., Seoul (2002)

[16] Rostrup-Nielsen JR, Hansen JHB, Journal of Catalysis., 144, 38 (1993)

[17] Takanabe K, Nagaoka K, Nariai K, Aika K, J. Catal., 232(2), 268 (2005)

[18] Nagaoka K, Takanabe K, Aika K, Appl. Catal. A: Gen., 268(1-2), 151 (2004)

[19] Hou ZY, Yashima T, Catal. Lett., 89(3-4), 193 (2003)

[20] Hong JS, Hwang JS, Jun KW, Sur JC, Lee KW, Appl. Catal. A: Gen., 218(1-2), 53 (2001)

[21] Nurunnabi M, Murata K, Okabe K, Inaba M, Takahara I, Catalysis Communications., 8, 1531 (2007)

[22] Zhang JG, Wang H, Dalai AK, J. Catal., 249(2), 300 (2007)

[23] Backman LB, Rautiainen A, Krause AOI, Lindblad M, Catal. Today, 43(1-2), 11 (1998)

[24] O¨ zkara-Aydınog˘vlu S, Erhan Aksoylu A, Catalysis Communications., 11, 1165 (2010)

[25] Ocsachoque M, Pompeo F, Gonzalez G, Catal. Today, 172(1), 226 (2011)