화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.1, 74-82, January, 2014
DOI10.1016/j.jiec.2013.04.024  Export Citation
Synthesis and characterization of diethanolamine-impregnated cross-linked polyvinylalcohol/glutaraldehyde membranes for CO2/CH4 separation
Mona Zamani Pedram, Mohammadreza Omidkhah†, and Abtin Ebadi Amooghin
  • Chemical Engineering Department, Tarbiat Modares University, Tehran, Iran
E-mail:
In this research, the cross-linking of diethanolamine (DEA) impregnated poly(vinyl alcohol) (PVA) on polytetrafluoroethylene (PTFE) by glutaraldehyde (GA) with different blend compositions (GA/PVA: 0.5, 1, 3, 5, 7 ratio%) was performed in the absence of an acid catalyst and organic solvents in order to avoid any interference in CO2 facilitation reaction with DEA. The fabricated membranes were characterized by differential scanning calorimetry (DSC), Fourier transform infrared (FTIR) and scanning electron microscopy (SEM). Furthermore, the effects of cross-linking agent content, feed pressure and composition as well as stability on CO2/CH4 transport properties were investigated in both pure and mixed gas experiments. The cross-linked membranes showed reasonable CO2/CH4 permselectivities in comparison with uncross-linked membranes. The best-yield CO2-selective membranes (DEA-PVA/GA(1 wt%)/PTFE) represented the best CO2/CH4 selectivity of 91.13 and 665 for pure and mixed gas experiments, respectively.
Keywords:Carbon dioxide;Facilitated transport;Poly(vinyl alcohol);Diethanolamine;Glutaraldehyde
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