화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.1, 29-36, January, 2014
DOI10.1016/j.jiec.2013.04.030  Export Citation
Polymer-supported IBX amide for mild and efficient oxidation reactions
Hyung-Seok Jang, Yo-Han Kim, Young-O Kim, Sang-Myung Lee1, Jung Won Kim2, Woo-Jae Chung3, †, and Yoon-Sik Lee†
  • School of Chemical and Biological Engineering, Seoul National University, Kwanak-Ku, Seoul, Republic of Korea
  • 1Department of Chemical Engineering, Kangwon National University, Chuncheon, Kangwondo 200-701, Republic of Korea
  • 2Department of Chemical Engineering, Kangwon National University, Samcheok, Kangwon-Do 245-711, Republic of Korea
  • 3Department of Genetic Engineering, Sungkyunkwan University, Jangan-gu, Suwon, Gyeonggi-do 440-746, Republic of Korea
E-mail:,
A facile simple preparation of polymer-supported IBX amide (IBX amide resin) from chloromethyl polystyrene resin was demonstrated. The IBX amide resins were prepared with high loading levels (~1.40 mmol g^(-1)). These reagents were found to be mild and efficient oxidants through oxidation of a range of alcohols, sulfides and phosphites to the corresponding carbonyl, sulfoxide and phosphate compounds without over-oxidation at room temperature. Consumed IBX amide resins were reused up to five times without significant loss of oxidative activity after repetitive regeneration.
Keywords:Polymer-supported oxidant;IBX amide resin;Alcohol;Sulfide;Phosphite;Oxidation
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