화학공학소재연구정보센터
Journal of Chemical Physics, Vol.100, No.6, 4065-4076, 1994
On the Interpretation and Rotational Assignment of Degenerate 4-Wave-Mixing Spectra - 4-Photon Line Strengths for Crossover Resonances in No-A (2)Sigma(+)-X (2)Pi
We present here a set of equations specifically adapted to simulation of fully resonant, high-resolution, phase-conjugate degenerate four-wave mixing (DFWM) in molecular gases. Signal-intensity dependence on molecular wave functions, lifetimes, and laser beam polarizations is explicitly included in these equations. The emphasis of the presentation is on both physically intuitive interpretation and a practical, "cookbook" approach to spectral simulation. We present experimental verification of our calculations drawn from the spectrum of dilute Nd in N-2 at low pressures. Both degenerate two-level and three-level (crossover) resonances were observed. The experimental spectral intensities are accurately reproduced by the expressions presented here. We point out some of the Subtleties of DFWM spectra that could be used as aids to interpretation, especially the use of laser polarization as a probe for spectral line assignments.