Journal of Chemical Physics, Vol.100, No.2, 1456-1459, 1994
Chemical-Potentials of Hard-Sphere Solutes in Hard-Sphere Solvents - Monte-Carlo Simulations and Analytical Approximations
We report Monte Carlo simulation results for the excess chemical potentials of infinitely dilute hard spheres, and the distribution of cavity sizes, in a hard sphere fluid. The results are compared with previous simulations and analytical expressions derived from the Boublik-Mansoori-Carnahan-Starling-Leland equation of state and scaled particle theory.