Journal of Chemical Physics, Vol.99, No.12, 9836-9841, 1993
Ellipsometric Measurement of a Surface Amplitude Ratio Near a Critical End-Point
We present the experimental determination of a universal surface amplitude ratio near a critical end point. From ellipsometric measurements on five critical binary liquid mixtures, three with an upper critical point and two with a lower critical point, we obtain a value for the modified critical adsorption amplitude ratio of R(ma) = 1.18 +/- 0. 13, where the error represents three standard deviations. Reasonable agreement is obtained with the theoretical results of H. W. Diehl and A4. Smock [Phys. Rev. B 47, 5841 (1993)], from which we obtain R(ma) = 1.33.
Keywords:LIGHT-SCATTERING;CRITICAL ADSORPTION;BINARY MIXTURE;LIQUID-MIXTURE;VISCOSITY;COMBINATIONS;NITROBENZENE;INTERFACE;TENSIONS;PROFILE